Cyclopropylboronic acid

Cyclopropylboronic acid Basic information

Product Name:	Cyclopropylboronic acid
Synonyms:	AKOS BRN-0457;CYCLOPROPYLBORONIC ACID;CYCLOPROPYLBORONIC ACID,MONOHYDRATE;BORONIC ACID, CYCLOPROPYL- (9CI);;Cyclopropylboronic acid (contains varying amounts of anhydride);CYCLOROPYLBORONIC ACID;Boronic acid, cyclopropyl- (9CI);Cyclopropylboronic acid 95%;Cyclopropylboronic acid, tech. 85%
CAS:	411235-57-9
MF:	C3H7BO2
MW:	85.9
EINECS:	609-890-0
Product Categories:	Alkyl Boronic Acids;Boronic Acids;Boronic Acids and Derivatives;Chemical Synthesis;Organometallic Reagents;Boronic Acids & Esters;Cyclopropyl;Organoborons;Boronic acid;CHIRAL CHEMICALS;Boronic Acids & Esters;Ring Systems;Alkyl;Boronic Acids;Boronic Acids and Derivatives;BORONICACID;blocks;BoronicAcids;bc0001
Mol File:	411235-57-9.mol

Cyclopropylboronic acid Chemical Properties

Melting point	90-95 °C (lit.)
Boiling point	205.1±23.0 °C(Predicted)
density	1.11±0.1 g/cm3(Predicted)
storage temp.	-20°C
solubility	DMSO
pka	10.49±0.20(Predicted)
form	Powder
color	white
Sensitive	moisture sensitive
InChIKey	WLVKDFJTYKELLQ-UHFFFAOYSA-N
CAS DataBase Reference	411235-57-9(CAS DataBase Reference)

Safety Information

Hazard Codes	Xn,T
Risk Statements	22-36-61-60-36/37/38
Safety Statements	26-36-45-53-37/39
WGK Germany	3
TSCA	No
HazardClass	IRRITANT, IRRITANT-HARMFUL
HS Code	29319090

MSDS Information

Provider	Language
SigmaAldrich	English

Cyclopropylboronic acid Usage And Synthesis

Chemical Properties	White to off-white powder
Uses	Reagent used for• ;Microwave-assisted copper(II)-catalyzed N-cyclopropylation1• ;Nickel- and copper-catalyzed Suzuki-Miyaura coupling reaction of arenes2• ;Palladacycle-catalyzed Suzuki-cross coupling of aryl halides with cyclopropylboronic acid3• ;Palladium(0)-catalyzed cyclopropane C-H bond functionalization4• ;Palladium-catalyzed decarboxylative coupling5• ;Palladium-catalyzed ligand-directed oxidative functionalization of cyclopropanes6• ;Palladium-catalyzed Suzuki coupling reaction7Reagent used in Preparation of• ;Diaryl ketones by arylation
Uses	suzuki reaction
Uses	Cyclopropylboronic Acid is an organoboronic acid commonly used in highly efficient Suzuki coupling reactions.

Cyclopropylboronic acid Preparation Products And Raw materials

Raw materials	Cyclopropylboronic acid methyliminodiacetic acid anhydride-->Potassium cyclopropyltrifluoroborate-->Cyclopropylboronic acid pinacol ester-->Cyclopropylmagnesium bromide-->Diiodomethane
Preparation Products	Benzene, 1,4-dicyclopropyl-2-nitro--->alpha-cyclopropylstyrene-->2-BroMo-5-cyclopropylpyrazine-->2-broMo-5-cyclopropylpyridine-->3-Cyclopropylbenzoic acid-->4-bromo-1-cyclopropyl-1H-pyrazole-->4,4'-DICHLORODIPHENYL DISULFIDE-->5-cyclopropyl-2-thiophenecarboxaldehyde-->3-CYCLOPROPYL-5-(TRIFLUOROMETHYL)ANILINE-->3-Bromo-5-cyclopropylisonicotinonitrile

cyclopropylhydrazine hydrochloride CYCLOBUTYL-ACETIC ACID tert-butyl cyclopropanecarboxylate Cyclohexylboronic acid CYCLOHEXYLBORONIC ACID DIETHANOLAMINE ESTER Cyclopropane-1-carboximidamide hydrochloride Propiconazole Ciprofloxacin hydrochloride Cyclopropylboronic acid methyliminodiacetic acid anhydride,Cyclopropylboronic acid MIDA ester Cyclopropyl acetylene Ethyl 2-(Chlorosulfonyl)acetate Ascoric Acid CYCLOPROPYLBORONIC ACID, HEXYLENE GLYCOL CYCLIC ESTER Zinc borate Ciprofloxacin lactate 2-CYCLOPROPYL-5,5-DIMETHYL-1,3,2-DIOXABORINANE Dicyclopropane methylamine Cyclopropanecarbonitrile

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