TETRAKIS(DIMETHYLAMINO)TITANIUM

TETRAKIS(DIMETHYLAMINO)TITANIUM Basic information
Product Name:TETRAKIS(DIMETHYLAMINO)TITANIUM
Synonyms:Tetrakis(dimethylamino)titanium(IV), 99% TDMAT, 93-2240, contained in 50 ml Swagelok cylinder for CVD/ALD;Tetrakis(dimethylamino)titanium, (trace metal basis), 99.99%;Tetrakis(dimethylamino)titanium(IV), 99% TDMAT;Tetrakis(diMethylaMino)titaniuM, 99.99%, (trace Metal basis);Tetrakis(diMethylaMino)titaniuM, 99.99% 25GR;Tetrakis(DiMethylaMino)TitaniuM (Metals Basis);Tetrakis(diMethylaMino)titaniuM, 99.99% Metals basis;Tetrakis(diMethylaMido)titaniuM(IV) 99.999% trace Metals basis
CAS:3275-24-9
MF:C2H7NTi
MW:92.95
EINECS:221-904-3
Product Categories:metal amide complex;ALD Precursors;Classes of Metal Compounds;Ti (Titanium) Compounds;Transition Metal Compounds
Mol File:3275-24-9.mol
TETRAKIS(DIMETHYLAMINO)TITANIUM Structure
TETRAKIS(DIMETHYLAMINO)TITANIUM Chemical Properties
Melting point <4°C
Boiling point 50 °C0.5 mm Hg(lit.)
density 0.947 g/mL at 25 °C(lit.)
refractive index 1.55
Fp -22 °F
storage temp. Flammables area
form liquid
Specific Gravity0.96
color yellow to orange
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
Sensitive Moisture Sensitive
InChIKeyMNWRORMXBIWXCI-UHFFFAOYSA-N
CAS DataBase Reference3275-24-9(CAS DataBase Reference)
NIST Chemistry ReferenceTetrakis(dimethylamino)titanium(3275-24-9)
EPA Substance Registry SystemMethanamine, N-methyl-, titanium(4+) salt (3275-24-9)
Safety Information
Hazard Codes F,C,Xi
Risk Statements 11-14-34
Safety Statements 16-26-36/37/39-43-45
RIDADR UN 3398 4.3/PG 1
WGK Germany 3
TSCA Yes
HazardClass 4.3
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
TETRAKIS(DIMETHYLAMINO)TITANIUM Usage And Synthesis
Chemical Propertiesclear yellow to orange liquid
UsesTetrakis(dimethylamido)titanium(IV) (TDMAT) is a precursor to titanium nitride (TiN) thin films by organometallic chemical vapor deposition (OMCVD)and titanium dioxide thin films by atomic layer deposition (ALD).TDMAT undergoes exothermal reaction with excess cyclopentadiene to yield tris(dimethylamido)(η5-cyclopentadienyl)titanium(IV).
UsesPrecursors Packaged for Depositions Systems
General DescriptionAtomic number of base material: 22 Titanium
TETRAKIS(DIMETHYLAMINO)TITANIUM Preparation Products And Raw materials
TETRAKIS(DIMETHYLAMINO)TIN Trityl tetrakis(pentafluorophenyl)borate TETRAKIS(DIMETHYLAMIDO)HAFNIUM(IV) TETRAKIS(ACETONITRILE)SILVER(I) TETRAFLUOROBORATE Tetrakis(triphenylphosphine)nickel TETRAKIS(ETHYLMETHYLAMINO)ZIRCONIUM TETRAKIS(DIETHYLAMINO)ZIRCONIUM Vanadium tetrakis(dimethylamide) Germanium dimethylamide TETRAKIS(DIETHYLAMINO)HAFNIUM TETRAKIS(DIMETHYLAMINO)ZIRCONIUM Tetrakis(ethylmethylamino)vanadium(IV) TETRAKIS(DIETHYLAMINO)TITANIUM TETRAKIS(ETHYLMETHYLAMINO)HAFNIUM Titanium TETRAKIS(ETHYLMETHYLAMINO)TITANIUM TETRAKIS(DIMETHYLAMINO)TITANIUM BIS(DIETHYLAMINO)BIS(DIMETHYLAMINO) TITANIUM, 99.99%

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