POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Basic information
Product Name:POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
Synonyms:POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE;potassium,(beta-4)-borate(1-hydrotris(1-methylpropyl)-;potassiumtri-sec-butylborohydride,calselect?k,;potassiumtri-sec-butylborohydride,calselect?k,intetrahydrofuran;K-SELECTRIDE(R);Potassium tri-sec-butylborohydride, 1M solution in tetrahydrofuran, AcroSeal;potassiumtri-sec-butylborohydride,calselectk,intetrahydrofur;(ca. 1.0Mol/L in Tetrahydrofuran)
CAS:54575-49-4
MF:C12H25BK
MW:219.24
EINECS:259-241-7
Product Categories:B (Classes of Boron Compounds);Classes of Metal Compounds;K (Potassium) Compounds (excluding simple potassium salts);Reduction;Synthetic Organic Chemistry;Tetrahydroborates;Typical Metal Compounds;metal alkyl
Mol File:54575-49-4.mol
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Structure
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Chemical Properties
density 0.913 g/mL at 25 °C
Fp 1 °F
storage temp. Flammables + water-Freezer (-20°C)e area
form Solution
color Clear slightly yellow
Sensitive moisture sensitive
EPA Substance Registry SystemBorate(1-), hydrotris(1-methylpropyl)-, potassium, (T-4)- (54575-49-4)
Safety Information
Hazard Codes F,C
Risk Statements 11-15-34-37-19-14/15-40
Safety Statements 16-26-36/37/39-43-45
RIDADR UN 3399 4.3/PG 1
WGK Germany 3
10
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Usage And Synthesis
Chemical Propertiesclear slightly yellow solution
UsesReducing reagent. Reactant for: Preparation of a PCP-pincer palladium hydride-K-Selectride complex. Formation of P-H, P-C, and C-H bonds by hydride attack. Stereoselective conjugate hydride reduction reactions.
UsesMild reducing agents in organic synthesis.
Uses
  • Reducing reagent

Reactant for:
  • Preparation of a PCP-pincer palladium hydride-K-Selectride complex
  • Formation of P-H, P-C, and C-H bonds by hydride attack
  • Stereoselective conjugate hydride reduction reactions
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Preparation Products And Raw materials
Triethylborane POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE TRI-SEC-BUTYLBORANE POTASSIUM TRIETHYLBOROHYDRIDE Potassium hydride TRIMETHYLBORON KS-SELECTRIDE(R) Potassium borohydride

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