Diethyl 2-bromo-2-methylmalonate

Diethyl 2-bromo-2-methylmalonate Basic information
Product Name:Diethyl 2-bromo-2-methylmalonate
Synonyms:2-BROMO-2-METHYLMALONIC ACID DIETHYL ESTER;DIETHYL BROMOMETHYLMALONATE;DIETHYL 2-BROMO-2-METHYLMALONATE;2-Brom-2-methylmalonic acid diethylester;2-BROMO-2-METHYLPROPANDIOIC ACID DIETHYL ESTER;2-(bromomethyl)-propanedioic acid diethyl ester;Diethyl 2-bromo-2-methylmalonate, 98+%;Diethyl-2-Bro-2-Methylmalonate
CAS:29263-94-3
MF:C8H13BrO4
MW:253.09
EINECS:249-541-6
Product Categories:Pharmaceutical Intermediates;TheMalonateRamificationProducts;C8 to C9;Carbonyl Compounds;Esters
Mol File:29263-94-3.mol
Diethyl 2-bromo-2-methylmalonate Structure
Diethyl 2-bromo-2-methylmalonate Chemical Properties
Boiling point 105-106 °C (5 mmHg)
density 1.325 g/mL at 25 °C (lit.)
refractive index n20/D 1.449(lit.)
Fp >230 °F
storage temp. Inert atmosphere,Room Temperature
form clear liquid
color Colorless to Almost colorless
BRN 1779673
CAS DataBase Reference29263-94-3(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 34-20/21/22
Safety Statements 26-36/37/39-45
RIDADR UN 3265 8/PG 2
WGK Germany 3
HS Code 2917.19.7050
HazardClass 8
PackingGroup III
MSDS Information
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Diethyl 2-bromo-2-methylmalonate Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS LIQUID
UsesDiethyl 2-bromo-2-methylmalonate was used to investigate the 1,2,2,6,6-pentamethylpiperidine as an effective reducing agent for the radical chain conversion of primary bromoesters to the corresponding esters. It was used in the synthesis of polystyrene macroinitiator via atom transfer radical polymerization.
General DescriptionDiethyl 2-bromo-2-methylmalonate acts as initiator during the atom transfer radical polymerization of methyl methacrylate.
Diethyl 2-bromo-2-methylmalonate Preparation Products And Raw materials
Preparation ProductsETHYL 2-METHYL-7-NITRO-3-OXO-3,4-DIHYDRO-2H-1,4-BENZOXAZINE-2-CARBOXYLATE-->Ethyl 3,4-dihydro-2-methyl-6-nitro-3-oxo-2H-1,4-benzoxazine-2-carboxylate-->2-Methyl-2-(phenylMethoxy)propanedioic Acid 1-Ethyl Ester
Diethyl ketomalonate Diethyl cyanomethylphosphonate Ethyl bromodifluoroacetate Diethyl 2-ethyl-2-phenylmalonate Diethyl isopropylmalonate Diethyl phenylmalonate Diethyl bis(hydroxymethyl)malonate Diethyl phthalate Dimethyl malonate Diethyl butylmalonate 3-Bromoanisole DIETHYL DIETHYLMALONATE Diethyl methylmalonate DIETHYL DIMETHYLMALONATE Mefenpyr-diethyl Diethyl chloromalonate Diethyl carbonate Diethyl ethylmalonate

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