2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE

2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE Basic information
Product Name:2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE
Synonyms:TRIFLUORETHYLTOSYLATE;TRIFLUOROETHANOL TOSYLATE;P-TOLUENESULFONIC ACID 2,2,2-TRIFLUOROETHYL ESTER;2,2,2-trifluoro-, p-toluenesulfonate;o-(p-tosyl)a,a,a,-trifluoroethanol;2,2,2-Trifluoroethyl 4-methylbenzenesulphonate, 2,2,2-Trifluoroethyl tosylate;2,2,2-Trifluoroethyl toluene-4-sulphonate 98%;2,2,2-Trifluoroethyl p-toluenesulfonate 99%
CAS:433-06-7
MF:C9H9F3O3S
MW:254.23
EINECS:207-085-5
Product Categories:Fluorinated Building Blocks;Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds;Synthetic Organic Chemistry;Organic Building Blocks;Sulfur Compounds;Tosylates;blocks;BuildingBlocks;FluoroCompounds;API intermediates
Mol File:433-06-7.mol
2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE Structure
2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE Chemical Properties
Melting point 36-38 °C(lit.)
Boiling point 87-92 °C0.1 mm Hg(lit.)
density 1 g/cm3
Fp >230 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform (Sparingly), Methanol (Sparingly)
form Solid
color White to Off-White
Sensitive Moisture Sensitive
BRN 2699394
Stability:Hygroscopic
InChIKeyIGKCQDUYZULGBM-UHFFFAOYSA-N
CAS DataBase Reference433-06-7(CAS DataBase Reference)
NIST Chemistry ReferenceEthanol, 2,2,2-trifluoro-, 4-methylbenzenesulfonate(433-06-7)
EPA Substance Registry SystemEthanol, 2,2,2-trifluoro-, 4-methylbenzenesulfonate (433-06-7)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
TSCA T
HazardClass IRRITANT
HS Code 29049090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE Usage And Synthesis
Chemical PropertiesWHITE CRYSTALLINE SOLID
Uses2,2,2-Trifluoroethyl Tosylate is a trifluoroethylation agent used in the preparation of 2,2,2-trifluoroethyl phenyl sulfone, a potential 2,2,2-trifluoroethyl pronucleophile.
2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE Preparation Products And Raw materials
Preparation ProductsBenzene, [(2,2,2-trifluoroethoxy)methyl]--->Bicyclo[2.2.1]heptane, 2-(2,2-difluoroethenyl)--->2,2,2-TRIFLUOROETHYL METHYL ETHER-->Ethane, 1,1,1-trifluoro-2-(methylthio)--->Ethanone, 1-[3-(2,2,2-trifluoroethoxy)phenyl]-
HEXAFLUOROISOPROPYL TOSYLATE P-TOLUENESULFINIC ACID Methyl toluenesulfonate p-Toluenesulfonic acid BENZENESULFINIC ACID 2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE METHYL BENZENESULFINATE Thiophenol Ethyl methanesulfonate Benzenesulfonic acid 1-(DIETHOXYPHOSPHORYL)-2,2,2-TRIFLUOROETHYL 4-METHYLBENZENESULFONATE 2,2,2-Trifluoroethanol Ethyl benzenesulphonate METHYL MERCAPTAN 2-Fluoroethyl 4-methylbenzenesulfonate Ethyl p-toluenesulfonate Sulphur 2,2-Difluoroethanol

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