1-Nitronaphthalene

1-Nitronaphthalene Basic information
Product Name:1-Nitronaphthalene
Synonyms:1-NITRONAPHTHALENE;ALPHA-NITRONAPHTHALENE;1-nitro-naphthalen;naphthalene,alpha-nitro;NCI-C01956;nitrol(pesticide);1-Nitronaphthalene (purity);1-Nitronphthalene
CAS:86-57-7
MF:C10H7NO2
MW:173.17
EINECS:201-684-5
Product Categories:Building Blocks;Chemical Synthesis;Nitro Compounds;Nitrogen Compounds;Organic Building Blocks;Nitro-PAH;Alphabetic;Environmental CRM;N;Intermediates of Dyes and Pigments;Nitro Compounds;Nitrogen Compounds;Organic Building Blocks;NA - NIApplication CRMs
Mol File:86-57-7.mol
1-Nitronaphthalene Structure
1-Nitronaphthalene Chemical Properties
Melting point 56 °C
Boiling point 304 °C(lit.)
density 1.223 g/mL at 25 °C(lit.)
refractive index 1.5200 (estimate)
Fp 164 °C
storage temp. 2-8°C
solubility H2O: insoluble
form neat
Specific Gravity1.223
color Light Yellow To Yellow
Water Solubility 0.022 g/L
Merck 14,6613
BRN 1867714
Stability:Stable. Combustible. Incompatible with oxidizing agents, strong reducing agents. Mixtures with sulfuric or nitric acid are dangerous.
InChIKeyRJKGJBPXVHTNJL-UHFFFAOYSA-N
CAS DataBase Reference86-57-7(CAS DataBase Reference)
IARC3 (Vol. 46) 1989
NIST Chemistry ReferenceNaphthalene, 1-nitro-(86-57-7)
EPA Substance Registry System1-Nitronaphthalene (86-57-7)
Safety Information
Hazard Codes F,T,N
Risk Statements 11-25-51/53-40-36/37/38-23/24/25
Safety Statements 16-45-60-61-28A-36/37/39-26
RIDADR UN 2538 4.1/PG 3
WGK Germany 2
RTECS QJ9720000
Hazard Note Flammable/Toxic
HazardClass 4.1
PackingGroup III
HS Code 29042000
Hazardous Substances Data86-57-7(Hazardous Substances Data)
MSDS Information
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1-Nitronaphthalene English
SigmaAldrich English
ACROS English
ALFA English
1-Nitronaphthalene Usage And Synthesis
Chemical Propertiesyellow crystalline solid
UsesUsually used to study excited state dynamics of 1-nitropthalene in nonpolar, aprotic and protic solvents.
Uses1-Nitronaphthalene as a nitroaromatic compound is studied for mutagenicity, as nitroaromatics are used in everyday products from polmers, dyes to drugs.
DefinitionChEBI: A mononitronaphthalene substituted by a nitro group at position 1.
General Description1-Nitronaphthalene is a mutagenic nitroaromatic compound present in diesel exhaust and it causes acute liver and lung toxicity in rodents. 1-Nitronaphthalene is a cytochrome P450-bioactivated, nonciliated bronchiolar epithelial (Clara) cell cytotoxicant .
Biochem/physiol Actions1-Nitronaphthalene binds covalently to protein and forms adducts in the rat airway epithelium in vivo.
Safety ProfilePoison by intraperitoneal route. Mutation data reported. A skin, eye, and mucous membrane irritant. Flammable solid and combustible liquid when exposed to heat or flame. To fight fire, use CO2, dry chemical, or water spray. Explosive reaction with nitric acid + sulfuric acid above 60°C. Forms a sensitive explosive mixture with tetranitromethane. When heated to decomposition it emits toxic fumes of NOx. See also 2-NITRONAPHTHALENE and NITRO COMPOUNDS OF AROMATIC HYDROCARBONS.
Purification MethodsFractionally distil 1-nitronaphthalene under reduced pressure, then crystallise it from EtOH, aqueous EtOH or heptane. Chromatograph it on alumina with *benzene/pet ether as eluent. It sublimes in vacuo. The 1:1 picrate complex has m 72o (from EtOH). [Beilstein 5 H 553, 5 III 1593, 5 IV 1673.]
4-NITRO-1-NAPHTHALENE ACETIC ACID 1-bromo-8-nitronaphthalene 3-bromo-1-nitronaphthalene 1-METHOXY-4-NITRONAPHTHALENE N-(2 4-DINITRO-1-NAPHTHYL)-P-TOLUENESULFONAMIDE 1-bromo-3-nitronaphthalene 2-bromo-7-nitronaphthalene 2-METHYL-1-NITRONAPHTHALENE TRITON 4-Nitronaphthalene-1,8-dicarboxylic anhydride 1-Phenyl-2-nitropropene 1,3-DINITRONAPHTHALENE 1,3-DINITROPYRENE 1,8-Dinitronaphthalene 2,4-DINITRO-1-NAPHTHOL 2-bromo-6-nitronaphthalene 6-NITRONAPHTHALENE-1,2-AZOXY-4-SULFONIC ACID,4-Diazonio-3-hydroxy-7-nitronaphthalene-1-sulfonate 1-chloro-8-nitronaphthalene

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