POTASSIUM 2-METHYL-2-BUTOXIDE

POTASSIUM 2-METHYL-2-BUTOXIDE Basic information
Product Name:POTASSIUM 2-METHYL-2-BUTOXIDE
Synonyms:2-methyl-2-butanopotassiumsalt;potassium-amylate;potassiumt-amylate,kta;potassiumt-amylate,kta,in;potassiumt-amylate,kta,incyclohexane;potassiumt-amylate,kta,intoluene;POTASSIUM TERT-PENTOXIDE;POTASSIUM TERT-PENTYLATE
CAS:41233-93-6
MF:C5H13KO
MW:128.26
EINECS:255-272-5
Product Categories:
Mol File:41233-93-6.mol
POTASSIUM 2-METHYL-2-BUTOXIDE Structure
POTASSIUM 2-METHYL-2-BUTOXIDE Chemical Properties
Melting point >160°C dec
Boiling point 81°C
density 0.90 g/mL at 20 °C
vapor pressure 0.001-0.49Pa at 20-90℃
Fp 4°C
storage temp. Inert atmosphere,Room Temperature
form Liquid
Specific Gravity0.8
Water Solubility Reacts with water.
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 4149025
Exposure limitsACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3)
InChIKeyZRLVQFQTCMUIRM-UHFFFAOYSA-N
EPA Substance Registry System2-Butanol, 2-methyl-, potassium salt (41233-93-6)
Safety Information
Hazard Codes F,C
Risk Statements 11-14-34-48/20-63-65-67-40-37-19
Safety Statements 26-36/37/39-43-45-62-16
RIDADR UN 2924 3/PG 2
WGK Germany 3
1-10
TSCA Yes
HazardClass 3
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
POTASSIUM 2-METHYL-2-BUTOXIDE Usage And Synthesis
UsesPotassium tert-pentyloxide is used in wide range of applications in organic synthesis, agrochemicals, pharmaceuticals, colorants and aroma chemicals. It is also used in manufacturing detergents and biodiesel. They also act as catalysts in polymerization and isomerizations.
UsesPotassium tert-pentoxide solution has been used as a base to synthesize [RuClPh(CO)(H2IMes)(PCy3)] from second-generation Grubbs metathesis catalyst, [RuCl2(=CHPh)(H2IMes)(PCy3)], (where H2IMes is 1,3-dimethyl-4,5-dihydroimidazol-2-ylidene and PCy3 is tricyclohexylphosphine) and benzyl alcohol. This complex is a solid, air-stable and highly active isomerization catalyst.
POTASSIUM 2-METHYL-2-BUTOXIDE Preparation Products And Raw materials
Preparation ProductsETHYL 4-METHOXYBENZOYLACETATE
Potassium tert-butoxide tert-Butyllithium PENTYLMAGNESIUM CHLORIDE ISOBUTYLLITHIUM Lithium tert-butoxide Sodium tert-pentoxide Magnesium tert-butoxide Sodium tert-butoxide Sodium carbonate POTASSIUM ISOPROPOXIDE POTASSIUM 2-METHYL-2-BUTOXIDE 2-Methyl-2-butanol

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