ChemicalBook Product Catalog Chemical Reagents Organic reagents Esters Carboxylic Acid Esters TERT-BUTYL PROPIOLATE

TERT-BUTYL PROPIOLATE

TERT-BUTYL PROPIOLATE Basic information
Product Name:TERT-BUTYL PROPIOLATE
Synonyms:Propargylic Acid tert-Butyl Ester Propiolic Acid tert-Butyl Ester;tert-butyl prop-2-ynoate;Propynoic acid tert-butyl ester;2-Propynoic acid,1,1-diMethylethyl ester;PROPARGYLIC ACID TERT-BUTYL ESTER;PROPIOLIC ACID TERT-BUTYL ESTER;TERT-BUTYL ACETYLENECARBOXYLATE;TERT-BUTYL PROPIOLATE
CAS:13831-03-3
MF:C7H10O2
MW:126.15
EINECS:
Product Categories:Building Blocks;C6 to C7;Carbonyl Compounds;Chemical Synthesis;Esters;Organic Building Blocks;Acetylenes;Acetylenic Carboxylic Acids & Their Derivatives
Mol File:13831-03-3.mol
TERT-BUTYL PROPIOLATE Structure
TERT-BUTYL PROPIOLATE Chemical Properties
Melting point 18-20 °C (lit.)
Boiling point 52-53 °C/27 mmHg (lit.)
density 0.919 g/mL at 25 °C (lit.)
refractive index n20/D 1.418(lit.)
Fp 82 °F
storage temp. Keep in dark place,Inert atmosphere,2-8°C
form Liquid
color Clear colorless to yellow
Sensitive Air Sensitive
BRN 1747175
InChIKeyXGTPDIIFEPTULX-UHFFFAOYSA-N
CAS DataBase Reference13831-03-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38
Safety Statements 26-36/37/39
RIDADR UN 3272 3/PG 3
WGK Germany 3
F 4.5-10-23
HazardClass 3.1
PackingGroup II
HS Code 29161995
MSDS Information
ProviderLanguage
SigmaAldrich English
TERT-BUTYL PROPIOLATE Usage And Synthesis
UsesTERT-BUTYL PROPIOLATE is used to prepare heterocycles,1,2 alkaloids,3 and unsaturated amino acids.4
Usestert-Butyl propiolate may be used in the preparation of heterocycles, alkaloids, and unsaturated amino acids.
General Descriptiontert-Butyl propiolate is an ester. It reacts with methimazole to afford tert-butyl (E)-3-(1-methyl-1H-imidazol-2-ylthio) acrylate. Crystallographic data for the lithium enolate of tert-butyl propiolate has been described..
TERT-BUTYL PROPIOLATE Preparation Products And Raw materials
Preparation Products1H-Imidazole-2,4-dicarboxylic acid, 4-(1,1-dimethylethyl) 2-ethyl ester-->1-(3-chloro-2-fluorophenyl)-1H-1,2,3-triazole-4-carboxylic acid
TERT-BUTYLDIMETHYL(2-PROPYNYLOXY)SILANE 2-tert-Butyl-1,4-benzoquinone TERT-BUTOXY ACETIC ACID Hydroxypropyl acrylate tert-Butyl N-(3-aminopropyl)-N-methylcarbamate tert-butyl 2-(chloromethyl)-1H-benzimidazole-1-carboxylate TERT-BUTYL 3-(4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-1H-PYRAZOL-1-YL)AZETIDINE-1-CARBOXYLATE Octadecyl acrylate tert-Butyldiphenylsilane 7-AMINO-3,4-DIHYDRO-1H-ISOQUINOLINE-2-CARBOXYLIC ACID TERT-BUTYL ESTER (4-IODO-PYRIDIN-3-YL)-CARBAMIC ACID TERT-BUTYL ESTER TERT-BUTYL-(2-IODO-ETHOXY)-DIMETHYL-SILANE 2-(N-Boc-aMinoMethyl)-5-chloropyridine TERT-BUTYL 4-AMINO-3-FLUOROPIPERIDINE-1-CARBOXYLATE tert-butyl 6-bromo-2H-pyrido[3,2-b][1,4]oxazine-4(3H)-carboxylate tert-butyl 2-oxo-8-azaspiro[4.5]decane-8-carboxylate (TERT.-BUTYLDIMETHYLSILYLOXY)ETHANOL DI-TERT-BUTYL ACETYLENEDICARBOXYLATE
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