2-Methylthiophene

2-Methylthiophene Basic information
Product Name:2-Methylthiophene
Synonyms:2-methyl-thiophen;alpha-methylthiophene;2-METHYLTHIOPHENE;2MT;2-Methylthiophene,98%;methylthiophene,2-methylthiophene;2-thiotolene;2-METHYLTHIOPHENE GC 99+%
CAS:554-14-3
MF:C5H6S
MW:98.17
EINECS:209-063-0
Product Categories:Heterocycle-oher series;Chemistry;Building Blocks;Heterocyclic Building Blocks;Thiophene&Benzothiophene;Heterocycles;Thiophenes;thiophene Flavor
Mol File:554-14-3.mol
2-Methylthiophene Structure
2-Methylthiophene Chemical Properties
Melting point -63 °C (lit.)
Boiling point 113 °C (lit.)
density 1.014 g/mL at 25 °C (lit.)
vapor pressure 47.6 mm Hg ( 37.7 °C)
refractive index n20/D 1.52(lit.)
Fp 45 °F
storage temp. 2-8°C
solubility immiscible
form Liquid
Specific Gravity1.025 (20℃)
color Clear colorless to yellow
Odorat 0.01 % in propylene glycol. sulfurous alliaceous onion roasted green
Odor Typesulfurous
Water Solubility immiscible
BRN 103734
InChIKeyXQQBUAPQHNYYRS-UHFFFAOYSA-N
LogP2.330
CAS DataBase Reference554-14-3(CAS DataBase Reference)
NIST Chemistry ReferenceThiophene, 2-methyl-(554-14-3)
EPA Substance Registry SystemThiophene, 2-methyl- (554-14-3)
Safety Information
Hazard Codes F,Xn,Xi
Risk Statements 11-22-36/37/38-37-2017/11/22
Safety Statements 16-37/39-26-36-33-7/9
RIDADR UN 1993 3/PG 2
WGK Germany 3
RTECS XM9625000
10-13
TSCA T
HazardClass 3
PackingGroup II
HS Code 29349990
MSDS Information
ProviderLanguage
2-Methylthiophene English
SigmaAldrich English
ACROS English
ALFA English
2-Methylthiophene Usage And Synthesis
Chemical Propertiesclear colorless to slightly yellow liquid
Uses2-Methylthiophene, is used as a flavoring agent that naturally occurs in grilled and roasted beef, papaya, cooked shrimp, whiskey, and in trace amounts in roasted chicken;
DefinitionChEBI: 2-methylthiophene is a member of the class of thiophenes that is thiophene in which the hydrogen atom at position 2 is substituted by a methyl group. It has a role as a flavouring agent and a Maillard reaction product. It is a member of thiophenes and a volatile organic compound. It is functionally related to a thiophene.
Synthesis Reference(s)The Journal of Organic Chemistry, 14, p. 638, 1949 DOI: 10.1021/jo01156a016
Tetrahedron Letters, 22, p. 2443, 1981 DOI: 10.1016/S0040-4039(01)92928-4
METHYL 2-([(2-CHLOROETHOXY)CARBONYL]AMINO)-4-METHYLTHIOPHENE-3-CARBOXYLATE METHYL 3-CHLORO-4-METHYLTHIOPHENE-2-CARBOXYLATE 5-NITROTHIOPHENE-2-CARBOXALDEHYDE 2-Carboxy-5-methylthiophene 2-AMINO-5-METHYLTHIOPHENE-3-CARBONITRIL METHYL 3-(((1,3-DIOXOINDAN-2-YLIDENE)METHYL)AMINO)-4-METHYLTHIOPHENE-2-CARBOXYLATE METHYL 4-METHYLTHIOPHENE-2-CARBOXYLATE 2-(4-CYANOBENZOYL)-5-METHYLTHIOPHENE 2-(5-METHYL-2-THIENYL)PYRROLIDINE 4-CHLORO-2-METHYL-THIENO[2,3-D]PYRIMIDINE Ethyl 2-thiophenecarboxylate 2-(4-Fluorophenyl)-5-[(5-iodo-2-methylphenyl)methyl]thiophene METHYL 3-(2-[2-(ETHOXYCARBONYL)-4,4,4-TRIFLUORO-3-OXOBUT-1-ENYL]HYDRAZINO)-4-METHYLTHIOPHENE-2-CARBOXYLATE 2-AMINO-5-METHYL-THIOPHENE-3-CARBOXYLIC ACID ETHYL ESTER METHYL 3-FORMYLAMINO-4-METHYLTHIOPHENE-2-CARBOXYLATE 2-ACETYL-5-CHLOROTHIOPHENE N2-(2-(2-[4-(CHLOROMETHYL)BENZOYL]HYDRAZINO)-2-OXOETHYL)-4-METHYLTHIOPHENE-2-CARBOXAMIDE N'-(CHLOROACETYL)-4-ETHYL-5-METHYLTHIOPHENE-2-CARBOHYDRAZIDE

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