DIETHYL ALLYLPHOSPHONATE

DIETHYL ALLYLPHOSPHONATE Basic information

Product Name:	DIETHYL ALLYLPHOSPHONATE
Synonyms:	DIETHYL(PROP-1(E)-ENYL)PHOSPHONATE;DIETHYL(PROP-2-(E)-ENYL)PHOSPHONATE;DIETHYL-(ALLYLPHOSPHONAT);DIETHYL ALLYLPHOSPHONATE;DIETHYL-(2-PROPENYL)-PHOSPHONAT;DIETHYL(2-PROPENYL)PHOSPHONATE;DIETHYL (1-PROPENYL)PHOSPHONATE;AURORA KA-1466
CAS:	1067-87-4
MF:	C7H15O3P
MW:	178.17
EINECS:	619-646-5
Product Categories:	C-C Bond Formation;Horner-Wadsworth-Emmons Reagents;Olefination
Mol File:	1067-87-4.mol

DIETHYL ALLYLPHOSPHONATE Chemical Properties

Boiling point	46 °C/0.35 mmHg (lit.)
density	1,035 g/cm³
vapor pressure	55.2Pa at 25℃
refractive index	n20/D 1.4340(lit.)
Fp	224 °F
form	Liquid
color	Clear colorless
LogP	1.33 at pH7
Surface tension	56.4-60.9mN/m at 1g/L and 19℃
CAS DataBase Reference	1067-87-4(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
WGK Germany	3
HS Code	29319090

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English
ALFA	English

DIETHYL ALLYLPHOSPHONATE Usage And Synthesis

Chemical Properties	clear colorless liquid
Uses	Reactant for: Copolymerization of phosphonated allyl monomers and maleic anhydride Enantioselective synthesis of solamin type mono-THF acetogenins RCM reaction yielding oxaphospholene and oxaphosphinene heterocycles Synthesis of spongistatin 2 using Wittig coupling Stereoselective synthesis of pentacyclic furanosteroids Preparation of protected polyhydroxylated β -amino acid constitutents of microsclerodermins
Synthesis Reference(s)	Synthetic Communications, 22, p. 2219, 1992 DOI: 10.1080/00397919208019075 Synthesis, p. 563, 1986 DOI: 10.1055/s-1986-31704

DIETHYL ALLYLPHOSPHONATE Preparation Products And Raw materials

Raw materials	Phosphonic acid, P-(1E)-1-propen-1-yl-, diethyl ester-->Phosphonic acid, P-(1Z)-1-propen-1-yl-, diethyl ester-->Phosphorous acid, diethyl 2-propen-1-yl ester-->CARBONIC ACID ALLYL ETHYL ESTER-->Phosphonic acid, 1,2-propadienyl-, diethyl ester-->Triisopropyl phosphite-->Triethyl phosphite-->Diethyl phosphite-->Diisopropyl phosphite-->ALLYLMAGNESIUM BROMIDE-->Allyl chloride
Preparation Products	Triethyl phosphate-->Bromoethane

3-((DIETHOXYPHOSPHONATE)METHYL)-4-CHLORO-2-METHYL-1-PHENYL-3-PYRAZOLIN-5-ONE TRIETHYL 3-METHYL-4-PHOSPHONOCROTONATE DIETHYL 2-BUTENYLPHOSPHONATE TRIETHYL 4-PHOSPHONOCROTONATE DIETHYL (2-METHYLALLYL)PHOSPHONATE DIALLYL ALLYLPHOSPHONATE DIETHYL ALLYLPHOSPHONATE DIETHYL [3-CHLORO-3-(4-CHLOROPHENYL)-1-(DIMETHYLAMINO)ALLYL]PHOSPHONATE PERCHLORATE ZERENEX ZX000563 BIS(CHLOROPROPYL)-2-PROPENE PHOSPHONATE Di-n-butyl allylphosphonate, 97% DIETHYL [3-CHLORO-1-(DIMETHYLAMINO)-3-PHENYLALLYL]PHOSPHONATE PERCHLORATE DIISOPROPYLALLYLPHOSPHONATE DIETHYL [3-CHLORO-1-HYDROXY-3-(4-IODOPHENYL)ALLYL]PHOSPHONATE DIETHYL [3-(4-BROMOPHENYL)-3-CHLORO-1-HYDROXYALLYL]PHOSPHONATE DIETHYL [3-CHLORO-3-(4-CHLOROPHENYL)-1-HYDROXYALLYL]PHOSPHONATE DIETHYL [3-CHLORO-1-(DIMETHYLAMINO)-3-(4-METHYLPHENYL)ALLYL]PHOSPHONATE PERCHLORATE AURORA KA-1490

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