4-Biphenylcarboxylic acid

4-Biphenylcarboxylic acid Basic information
Product Name:4-Biphenylcarboxylic acid
Synonyms:4-CARBOXYDIPHENYL;4-BIPHENYLCARBOXYLIC ACID;LABOTEST-BB LT02084792;DIPHENYL-4-CARBOXYLIC ACID;RARECHEM AL BO 0062;TIMTEC-BB SBB008141;P-PHENYLBENZOIC ACID;(1,1’-biphenyl)-4-carboxylicacid
CAS:92-92-2
MF:C13H10O2
MW:198.22
EINECS:202-203-1
Product Categories:intermediate;Organic acids;Miscellaneous;Absolute Configuration Determination (Exciton Chirality CD Method);Analytical Chemistry;Enantiomer Excess & Absolute Configuration Determination;Exciton Chirality CD Method (for Hydroxyl Groups);Biphenyl derivatives;bc0001
Mol File:92-92-2.mol
4-Biphenylcarboxylic acid Structure
4-Biphenylcarboxylic acid Chemical Properties
Melting point 220-225 °C(lit.)
Boiling point 295.53°C (rough estimate)
density 1.1184 (rough estimate)
refractive index 1.5954 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility 0.03g/l
form Crystalline Powder
pka4.19±0.10(Predicted)
color White to beige
Water Solubility Insoluble in water.
BRN 973519
InChIKeyNNJMFJSKMRYHSR-UHFFFAOYSA-N
CAS DataBase Reference92-92-2(CAS DataBase Reference)
NIST Chemistry Reference[1,1'-Biphenyl]-4-carboxylic acid(92-92-2)
EPA Substance Registry System[1,1'-Biphenyl]-4-carboxylic acid (92-92-2)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/21/22-51-36-22
Safety Statements 37/39-26-36
WGK Germany 1
RTECS DV1925100
Hazard Note Irritant
TSCA Yes
HS Code 29163900
MSDS Information
ProviderLanguage
4-Biphenylcarboxylic acid English
SigmaAldrich English
ACROS English
ALFA English
4-Biphenylcarboxylic acid Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powder
UsesBiphenyl-4-carboxylic acid is employed in the synthesis, characterization of europium, terbium complexes.
Synthesis Reference(s)Synthetic Communications, 25, p. 3695, 1995 DOI: 10.1080/00397919508015507
Safety ProfileExperimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating vapors.
Purification MethodsCrystallise the acid from *C6H6/pet ether or aqueous EtOH. [Beilstein 9 IV 2479.]
2'-Nitro-4-biphenylcarboxylic acid 4'-(Heptyloxy)-4-biphenylcarboxylic acid p-(2-methylbutyl)phenyl ester 3'-NITRO-2-BIPHENYLCARBOXYLIC ACID 4-(Heptyloxy)-4'-biphenylcarboxylic acid 4-Butyl-4'-biphenylcarboxylic acid Bifendate 4-Biphenylcarboxylic acid ethyl ester 2'-Hydroxy-3-phenylpropiophenone 4'-n-Propyl-4-biphenylcarboxylic acid, 98%,4-Propyl-4'-biphenylcarboxylic acid 4-Heptyl-4'-biphenylcarboxylic acid 3-BIPHENYLCARBOXYLIC ACID ETHYL ESTER Diphenic acid 4'',4''''''-Azobis-(4-biphenylcarboxylic acid) CARBOXYLIC ACID Monoethanolaminebenzoate 2',4'-Difluoro-4,5-dihydroxy-3-biphenylcarboxylic acid Estradiol benzoate 3'-Nitro-4-biphenylcarboxylic acid

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