DIPHENYLIODONIUM CHLORIDE

DIPHENYLIODONIUM CHLORIDE Basic information
Product Name:DIPHENYLIODONIUM CHLORIDE
Synonyms:DIPHENYLIODONIUM CHLORIDE;chlorodiphenyliodonium;diphenyl-iodoniuchloride;Iodonium,diphenyl-,chloride;Diphenyliodinium;Iodonium,diphenyl-chloride;DIPHENYLIODONIUM CHLORIDE 97%;Diphenyliodonium chloride,97%
CAS:1483-72-3
MF:C12H10ClI
MW:316.57
EINECS:216-049-8
Product Categories:Diphenyliodonium Compounds;Hypervalent Iodine Compounds;Iodonium Sulfonium & Oxonium Compounds;Synthetic Organic Chemistry;Hypervalent Iodine;Oxidation;Synthetic Reagents
Mol File:1483-72-3.mol
DIPHENYLIODONIUM CHLORIDE Structure
DIPHENYLIODONIUM CHLORIDE Chemical Properties
Melting point 233-235 °C (subl.) (lit.)
density 1.6151 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility soluble in Methanol
form Powder
color White to light cream-yellow
Water Solubility Soluble in water and methanol.
Sensitive Light Sensitive
Merck 14,7464
BRN 3574977
InChIKeyRSJLWBUYLGJOBD-UHFFFAOYSA-M
CAS DataBase Reference1483-72-3(CAS DataBase Reference)
EPA Substance Registry SystemIodonium, diphenyl-, chloride (1483-72-3)
Safety Information
Hazard Codes T,Xi
Risk Statements 25-36/37/38
Safety Statements 26-36
RIDADR UN 2811 6.1/PG 3
WGK Germany 3
RTECS NN6651666
8
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
DIPHENYLIODONIUM CHLORIDE Usage And Synthesis
Chemical PropertiesWHITE TO LIGHT CREAM-YELLOW POWDER
UsesDiphenyliodonium chloride is used as a reagent for electrophilic phenylation . It is used as a reactant for copper-catalyzed cross coupling reactions of purinesband arylation of anilines. It is involved in the preparation of acetylenic arylselenide and (arylmethylene)oxindoles. Further, it is employed in the preparation of aryl alkynes through Sonogashira coupling reactions.
UsesReactant for:
  • Copper-catalyzed cross coupling reactions of purines and diaryliodonium salts
  • Synthesis of acetylenic arylselenides
  • Sonogashira coupling reactions for the preparation of aryl alkynes
  • C-H functionalization for synthesis of (arylmethylene)oxindoles
  • Arylation of anilines
  • Studies on the visible-light photosensitive system-dlourescein yellow-bis(di-Ph iodonium)
  • Investigating the properties of direct and sensitized photolysis of dispersed photoacid generators
DIPHENYLIODONIUM CHLORIDE Preparation Products And Raw materials
Dess-Martin periodinane DIPHENYLIODONIUM IODIDE Cyclohexene Acetyl chloride DIPHENYLIODONIUM BROMIDE Dichloroethane 4-METHOXYDIPHENYLIODONIUM CHLORIDE DIPHENYLENEIODONIUM CHLORIDE DIPHENYLIODONIUM CHLORIDE LABOTEST-BB LTBB005459 4,4'-DIFLUORODIPHENYLIODONIUM CHLORIDE

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