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Carbonyltris(triphenylphosphine)rhodium(I) hydride

Carbonyltris(triphenylphosphine)rhodium(I) hydride Basic information
Product Name:Carbonyltris(triphenylphosphine)rhodium(I) hydride
Synonyms:HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM (I);CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I);CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) HYDRIDE;CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRIDE;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL HYDRIDE;(betab-5-23)-rhodiu;carbonylhydrotris(triphenylphosphine)rhodium;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) &
CAS:17185-29-4
MF:3C18H15P.CO.HRh
MW:918.8
EINECS:241-230-3
Product Categories:metal carbonyl complexes;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Rh (Rhodium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Rh
Mol File:17185-29-4.mol
Carbonyltris(triphenylphosphine)rhodium(I) hydride Structure
Carbonyltris(triphenylphosphine)rhodium(I) hydride Chemical Properties
Melting point 150 °C (dec.) (lit.)
density 1.33
vapor pressure 0Pa at 25℃
storage temp. Keep in dark place,Inert atmosphere,2-8°C
solubility Soluble in hydrocarbons (e.g. benzene and toluene) with dissociation of phosphine ligands
form crystal
color light yellow
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Merck 14,9758
Exposure limitsACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
InChIKeyCEKFIOLKXHVOKA-UHFFFAOYSA-N
CAS DataBase Reference17185-29-4(CAS DataBase Reference)
NIST Chemistry Referencecarbonyl(hydrido)tris(triphenylphosphine)rhodium(17185-29-4)
EPA Substance Registry SystemRhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)- (17185-29-4)
Safety Information
Hazard Codes T
Risk Statements 23/24/25
Safety Statements 36/37/39-45-36/37
RIDADR UN 2811 6.1/PG 2
WGK Germany 1
F 10-23
TSCA Yes
HazardClass 4.3
PackingGroup III
HS Code 28439000
MSDS Information
ProviderLanguage
Carbonyltris(triphenylphosphine)rhodium(I) hydride English
SigmaAldrich English
ACROS English
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Carbonyltris(triphenylphosphine)rhodium(I) hydride Usage And Synthesis
Chemical Propertiesyellow crystals
UsesHydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation
UsesCatalyst.
Carbonyltris(triphenylphosphine)rhodium(I) hydride Preparation Products And Raw materials
Dipotassium hexachloroiridate Ruthenium tetroxide Tris(triphenylphosphine)rhodiu Rhodium triiodide Hydridotetrakis(triphenylphosphine)rhodium(I) Chloroiridic acid Tris(triphenylphosphine)ruthenium(II) chloride Iridium(IV) chloride Ruthenium dioxide Cyclopentadienyl manganese tricarbonyl Sodium hydride Carbonyltris(triphenylphosphine)rhodium(I) hydride Sodium triacetoxyborohydride Tributyltin Hydride Lithium Triethylborohydride Terphenyl, hydrogenated Triphenylphosphine Rhodium
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