2-(Dimethylamino)ethyl methacrylate

2-(Dimethylamino)ethyl methacrylate Basic information
Product Name:2-(Dimethylamino)ethyl methacrylate
Synonyms:Ageflex fm-1;ageflexfm-1;beta-(Dimethylamino)ethyl methacrylate;beta-(N,N-Dimethylamino)ethyl methacrylate;beta-(n,n-dimethylamino)ethylmethacrylate;beta-dimethylaminoethylmethacrylate;DMAEMA, 2-methyl-2-propenoic acid 2-(dimethylamino)ethyl ester;Ethanol, 2-(dimethylamino)-, methacrylate
CAS:2867-47-2
MF:C8H15NO2
MW:157.21
EINECS:220-688-8
Product Categories:organic chemical
Mol File:2867-47-2.mol
2-(Dimethylamino)ethyl methacrylate Structure
2-(Dimethylamino)ethyl methacrylate Chemical Properties
Melting point -50 °C
Boiling point 182-192 °C(lit.)
density 0.933 g/mL at 25 °C(lit.)
vapor density 5.4 (vs air)
vapor pressure <1 mm Hg ( 25 °C)
refractive index n20/D 1.439(lit.)
Fp 149 °F
storage temp. 2-8°C
solubility 500g/l soluble
form Liquid
pka8.18±0.28(Predicted)
color Clear colorless Liquid
explosive limit1.20%(V)
Water Solubility Less dense than water and insoluble in water.
BRN 1757048
Stability:Stable. Incompatible with strong acids, strong bases, strong oxidizing or reducing agents. May decompose on exposure to air and moisture. May undergo autopolymerization. Light sensitive.
InChIKeyJKNCOURZONDCGV-UHFFFAOYSA-N
LogP1.13 at 25℃
CAS DataBase Reference2867-47-2(CAS DataBase Reference)
NIST Chemistry ReferenceDimethylaminoethyl methacrylate(2867-47-2)
EPA Substance Registry System2-(Dimethylamino)ethyl methacrylate (2867-47-2)
Safety Information
Hazard Codes Xn,Xi,T
Risk Statements 21/22-36/38-43-34-23-22-21
Safety Statements 26-28-2-45-36/37/39
RIDADR UN 2522 6.1/PG 2
WGK Germany 1
RTECS OZ4200000
19
Autoignition Temperature255 °C
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 29221980
Hazardous Substances Data2867-47-2(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 1751 mg/kg
MSDS Information
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2-(Dimethylamino)ethyl methacrylate English
SigmaAldrich English
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2-(Dimethylamino)ethyl methacrylate Usage And Synthesis
Chemical Propertiescolourless liquid
Uses2-(Dimethylamino)ethyl methacrylate may be used in:
  • the synthesis of poly ((2-(Dimethylamino)ethyl methacrylate)
  • block copolymers of 2-(Dimethylamino)ethyl methacrylate and n-butyl methacrylate
  • amphiphilic AB block copolymers of 2-(Dimethylamino)ethyl methacrylate
UsesN,N-Dimethylaminoethyl-methacrylate is an amine activator in visible-light-cured dental-acrylic composite materials.
Uses2-(Dimethylamino)ethyl methacrylate is used in the synthesis of poly ((2-(Dimethylamino)ethyl methacrylate), block copolymers of 2-(Dimethylamino)ethyl methacrylate and n-butyl methacrylate and amphiphilic AB block copolymers of 2-(Dimethylamino)ethyl methacrylate. It is also used in the preparation of polymer.
General Description

A clear colorless liquid. Less dense than water and insoluble in water. Vapors heavier than air and corrosive to eyes and mucous membranes. May polymerize exothermically if heated or contaminated. If polymerization takes place inside a closed container, the container may rupture violently. Produces toxic oxides of nitrogen during combustion. Toxic by skin absorption, ingestion and inhalation. Used to make plastics and in textiles.

Air & Water ReactionsInsoluble in water.
Reactivity Profile2-(Dimethylamino)ethyl methacrylate is both an amine and an ester. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Health HazardTOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire HazardCombustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. May polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
Safety ProfilePoison by intraperitoneal route. Moderately toxic by ingestion and inhalation. A skin eye, and mucous membrane irritant. A powerful lachrymator. Flammable when exposed to sparks, heat, open flame, or oxidizers. To fight fire, use alcohol foam, dry chemical, spray. When heated to decomposition it emits toxic fumes of NOx. See also ESTERS.
2-(Dimethylamino)ethyl methacrylate Preparation Products And Raw materials
Preparation Productssuper absorbent resin synthesized by microwave cation ion radiation
2-Methoxyethyl methacrylate BEHENYL METHACRYLATE N,N-DIETHYLAMINOETHYL METHACRYLATE Q-SALT, METHOSULFATE BASIC BUTYLATED METHACRYLATE COPOLYMER IMP.C (EP):2-(DIMETHYLAMINO)ETHYL METHACRYLATE POLY((2-DIMETHYLAMINO)ETHYL METHACRYLATE) METHYL CHLORIDE QUATERNARY SALT RETRORSINE [2-(METHACRYLOYLOXY)ETHYL]TRIMETHYLAMMONIUM METHYL SULFATE 2-DIISOPROPYLAMINOETHYL METHACRYLATE 3-[Dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azaniumyl]propane-1-sulfonate 2-Propenoic acid, 2-methyl-, butyl ester, polymer with C12-15-alkyl methacrylate and 2-(dimethylamino)ethyl methacrylate Methacrylatoethyl trimethyl ammonium chloride PLATYPHYLLINE BITARTRATE N-(METHACRYLOXYETHYL)PHTHALIMIDE adipic acid, compound with 2-(dimethylamino)ethyl methacrylate (1:2) poly(isobutylene-co-2-(dimethylamino)ethyl methacrylate) 2-(1-AZIRIDINYL)-ETHYL METHACRYLATE 2-Propenoic acid, 2-methyl-, C12-20-alkyl esters, polymers with 2-(dimethylamino)ethyl methacrylate and Me methacrylate 2-METHACRYLOXYETHYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM CHLORIDE

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