Benzoguanamine

Benzoguanamine Basic information
Product Name:Benzoguanamine
Synonyms:2,4-diamino-6-phenyl-s-triazin;2-Phenyl-4,6-diamino-1,3,5-triazine;2-Phenyl-4,6-diamino-s-triazine;3,5-Triazine-2,4-diamine,6-phenyl-1;4,6-Diamino-2-phenyl-s-triazine;5-triazine,2,4-diamino-6-phenyl-3;5-triazine-2,4-diamine,6-phenyl-3;6-Phenyl-1,3,5-triazine-2,4-diyldiamine
CAS:91-76-9
MF:C9H9N5
MW:187.2
EINECS:202-095-6
Product Categories:Heterocyclic Compounds;Benzenes;Intermediates of Dyes and Pigments;Building Blocks;Chemical Synthesis;Heterocyclic Building Blocks;Triazines
Mol File:91-76-9.mol
Benzoguanamine Structure
Benzoguanamine Chemical Properties
Melting point 219-221 °C(lit.)
Boiling point 311.95°C (rough estimate)
density 1.4
vapor pressure 0Pa at 100℃
refractive index 1.6900 (estimate)
Fp >270°C
storage temp. Store below +30°C.
solubility 0.3g/l
pka4.22±0.10(Predicted)
form Solid
color White to Off-White
Specific Gravity1.425
PH6.5 (0.3g/l, H2O, 20℃)
Water Solubility 320mg/L at 25℃
Merck 14,1089
BRN 153223
InChIKeyGZVHEAJQGPRDLQ-UHFFFAOYSA-N
LogP1.38 at 25℃
CAS DataBase Reference91-76-9(CAS DataBase Reference)
NIST Chemistry Reference1,3,5-Triazine-2,4-diamine, 6-phenyl-(91-76-9)
EPA Substance Registry System1,3,5-Triazine-2,4-diamine, 6-phenyl- (91-76-9)
Safety Information
Hazard Codes Xn
Risk Statements 22-52/53
Safety Statements 61
WGK Germany 2
RTECS XY7000000
TSCA Yes
HazardClass IRRITANT
HS Code 29336980
Hazardous Substances Data91-76-9(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 1470 mg/kg
MSDS Information
ProviderLanguage
2,4-Diamino-6-phenyl-1,3,5-triazine English
SigmaAldrich English
ACROS English
ALFA English
Benzoguanamine Usage And Synthesis
Chemical Propertieswhite crystalline powder
UsesIn the manufacture of thermosetting resins, pesticides, pharmaceuticals and dyestuffs.
PreparationBenzoguanamine closely resembles melamine in that reaction with formaldehyde gives methylol derivatives and then resinous condensates. Butylated benzoguanamine-formaldehyde resins have found some use in surface coatings. In a typical preparation, benzoguanamine (1 mole) is heated with formalin (3 mole formaldehyde) at pH 8.3 and 70-80°C until the guanamine has dissolved. n-Butanol (9 mole) and a small amount of hydrochloric acid are added and the azeotrope distilled off until removal of water is complete. Like their melamine counterparts, butylated benzoguanamine-formaldehyde resins are most commonly used in admixture with alkyd resins. The resulting coatings are very similar to those based on melamine but they show improved resistance to alkalis.
Flammability and ExplosibilityNonflammable
Benzoguanamine Preparation Products And Raw materials
Raw materialsPETROLEUM ETHER-->Potassium hydroxide-->Benzonitrile-->1-Pentanol-->Dicyandiamide
Preparation ProductsVat Yellow 46
6-(4-CHLOROPHENYL)-1,3,5-TRIAZINE-2,4-DIAMINE 6-(2-CHLOROPHENYL)-1,3,5-TRIAZINE-2,4-DIAMINE BUTTPARK 44\01-42 BUTTPARK 4\01-80 BUTTPARK 148\02-96 2,6-DICHLORO-N-(4-[(2,6-DICHLOROISONICOTINOYL)AMINO]-6-[2-(2,4-DICHLOROPHENOXY)PHENYL]-1,3,5-TRIAZIN-2-YL)ISONICOTINAMIDE 6-(2,6-DIFLUOROPHENYL)-1,3,5-TRIAZINE-2,4-DIAMINE 3,4'-DIAMINODIPHENYLMETHANE 6-M-TOLYL-1,3,5-TRIAZINE-2,4-DIAMINE 2,4-DIAMINO-6-[4-(TRIFLUOROMETHYL)PHENYL]-1,3,5-TRIAZINE BUTTPARK 10\01-05 BUTTPARK 11\02-04 BUTTPARK 10\01-04 Amines, N-tallow alkyltrimethylenedi- MELAMINE RESIN PHENYL VALERATE BUTTPARK 1\01-50 BUTTPARK 1\01-19

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