ChemicalBook Product Catalog Organic Chemistry Phosphines Di-tert-butylchlorophosphane

Di-tert-butylchlorophosphane

Di-tert-butylchlorophosphane Basic information
Product Name:Di-tert-butylchlorophosphane
Synonyms:AURORA KA-1319;Bis(1,1-dimethylethyl)-phosphinous chloride;DI-T-BUTYLCHLOROPHOSPHINE;DI-T-BUTYLPHOSPHINOUS CHLORIDE;DI-TERT-BUTYLPHOSPHORUS CHLORIDE;DI-TERT-BUTYLCHLOROPHOSPHANE;DI-TERT-BUTYLCHLOROPHOSPHINE;DI-TERT-BUTYLCHLOROPHO
CAS:13716-10-4
MF:C8H18ClP
MW:180.66
EINECS:
Product Categories:organophosphine halide;Catalysis and Inorganic Chemistry;Ligand;Phosphorus Compounds;Phosphorus Precursors;Phosphines;Chlorophosphines;Achiral Phosphine;Alkyl Phosphine;P-Cl
Mol File:13716-10-4.mol
Di-tert-butylchlorophosphane Structure
Di-tert-butylchlorophosphane Chemical Properties
Melting point 2-3°C
Boiling point 48 °C/3 mmHg (lit.)
density 0.951 g/mL at 25 °C (lit.)
refractive index n20/D 1.482(lit.)
Fp 142 °F
solubility Miscible with terahydrofuran.
form Liquid
Specific Gravity0.951
color Clear colorless
Sensitive Air & Moisture Sensitive
InChIKeyMCRSZLVSRGTMIH-UHFFFAOYSA-N
CAS DataBase Reference13716-10-4(CAS DataBase Reference)
NIST Chemistry ReferencePhosphinous chloride, bis(1,1-dimethylethyl)-(13716-10-4)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45-25
RIDADR UN 3265 8/PG 2
WGK Germany 3
TSCA No
HazardClass 8
PackingGroup II
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
Di-tert-butylchlorophosphane Usage And Synthesis
Chemical PropertiesColorless to light yellow liqui
UsesDi-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.
UsesDi-tert-butylchlorophosphine is used as a catalyst in organic synthesis.
UsesBulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.
ApplicationBulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.
PrecautionsAir and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.
2-Di-t-butylphosphino-4-Methoxy-3,5,6-triMethyl-2',4',6'-tri-i-propylbiphenyl, Min. 98% [~1:1 Mixture with regioisoMer, 2-Di-t-butylphosphino-5-Methoxy-3,4,6-triMethyl-2',4',6'-tri-i-propylbiphenyl] Lithium Aluminum Hydride Tetrakis(hydroxymethyl)phosphonium sulfate DI-T-BUTYLPHOSPHINE OXIDE DIBROMO(CHLORODI-T-BUTYLPHOSPHINE)PALLADIUM(II) DIMER Di-tert-butylchlorophosphane T-BUTYLPHOSPHINE AURORA KA-1182 DICHLORO(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II) DIMER AURORA KA-1706 DICHLOROBIS(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II) DI-TERT-BUTYLCHLOROPHOSPHINE BORANE COMPLEX DI-1-ADAMANTYLPHOSPHINIC CHLORIDE DIBROMO(CHLORODI-TERT-BUTYLPHOSPHINE)PALLADIUM (II) DIMER
Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.