alpha-Amylcinnamaldehyde

alpha-Amylcinnamaldehyde Basic information
Product Name:alpha-Amylcinnamaldehyde
Synonyms:2-Benzylidenheptanal;AMYLZIMTALDEHYD ALPHA-;A-AMYL CINNAMIC ALDEHYDE;2-PENTYL-3-PHENYLPROPENOIC ALDEHYDE;2-benzylidene heptanal;2-(Phenylmethylene)-heptanal;ALPHA-PENTYLCINNAMALDEHYDE;ALPHA-N-AMYLCINNAMALDEHYDE
CAS:122-40-7
MF:C14H18O
MW:202.29
EINECS:204-541-5
Product Categories:A-B;Alphabetical Listings;Aldehydes;C10 to C21;Carbonyl Compounds;Flavors and Fragrances;Pharmaceutical Intermediates
Mol File:122-40-7.mol
alpha-Amylcinnamaldehyde Structure
alpha-Amylcinnamaldehyde Chemical Properties
Melting point 80°C
Boiling point 287-290 °C(lit.)
density 0.97 g/mL at 25 °C(lit.)
vapor pressure 0.133Pa at 25℃
FEMA 2061 | ALPHA-AMYLCINNAMALDEHYDE
refractive index n20/D 1.557(lit.)
Fp >230 °F
storage temp. 2-8°C
solubility Insoluble in water
form neat
color Pale-yellow oil or liquid
Odorfloral jasmine odor
Odor Typefloral
Water Solubility 181.69mg/L at 25℃
JECFA Number685
LogP2.498 at 25℃
CAS DataBase Reference122-40-7(CAS DataBase Reference)
NIST Chemistry ReferenceHeptanal, 2-(phenylmethylene)-(122-40-7)
EPA Substance Registry System2-(Phenylmethylene)heptanal (122-40-7)
Safety Information
Hazard Codes Xi,N
Risk Statements 36/37/38-51/53-43
Safety Statements 26-37/39-61-36/37
RIDADR UN 3082 9 / PGIII
WGK Germany 2
RTECS GD6825000
HazardClass 9
PackingGroup III
HS Code 29122990
Hazardous Substances Data122-40-7(Hazardous Substances Data)
ToxicityLD50 orl-rat: 3730 mg/kg FCTXAV 2,327,64
MSDS Information
ProviderLanguage
Amylcinnamaldehyde English
SigmaAldrich English
alpha-Amylcinnamaldehyde Usage And Synthesis
DescriptionAmylcinnamic aldehyde is an oxidation product of amylcinnamic alcohol, one component of the "fragrance mix" and can be found as a sensitizer in cases of contact dermatitis in bakers.
Chemical PropertiesLight yellow transparent liquid
Chemical Propertiesalpha-Amylcinnamaldehyde has been identified as an aroma volatile of black tea. It is a light yellow liquid with a floral, slightly fatty odor, which becomes reminiscent of jasmine when diluted.The aldehyde is relatively unstable and must be stabilized by antioxidants.
It is prepared from benzaldehyde and heptanal in the same way as cinnamaldehyde.
??-Amylcinnamaldehyde is a very popular fragrance substance for creating jasmine notes. It is stable to alkali and long-lasting; large quantities are used, particularly in soap perfumes.

Chemical Propertiesα-Amylcinnamaldehyde has a distinct floral (jasmine, lily) note.
OccurrenceReported found in black tea and soybean
Usesamyl cinnamal is used as a fragrance. Although it is naturally occurring in some plants, it is most often synthetically derived when used in cosmetic products.
UsesAmylcinnamaldehyde is a flavoring agent that is a yellow liquid with an odor similar to jasmine. It is insoluble in glycerin and propylene, soluble in fixed oils and mineral oil. It is obtained by chemical synthesis. It can be used alone or in combination with other flavoring substances or adjuvants. It is also termed amylcinnomaldehyde.
UsesRaw material in the production of perfumes; some perfumery uses (tuberose; peach; cherry; Estee; honeysuckle Chevrefeuille) Cross: amylcinnamic alcohol. AMYL CINNAMAL
PreparationBy condensation of n-amyl aldehyde with cinnamic aldehyde. This method of condensation of aromatic aldehydes with aliphatic aldehydes has the maximum yield in α-amylcinnamic aldehyde with little formation of the inferior homologs. The methyl, ethyl and propyl amylcinnamic aldehyde analogs exhibit a characteristic scent.
DefinitionChEBI: Alpha-Amylcinnamaldehyde is a member of cinnamaldehydes.
Taste threshold valuesTaste characteristics at 40 ppm: sweet, floral, spice-like with cinnamic and waxy nuance
General DescriptionThe short-term feeding studies in rats was carried out using α-amylcinnamaldehyde, a flavouring matter.
Flammability and ExplosibilityNotclassified
Contact allergensa-Amyl-cinnamic aldehyde is an oxidation product of amylcinnamic alcohol, a sensitizing fragrance, and one component of the “fragrance mix.” It can also be a sensitizer in bakers. It has to be mentioned by name in cosmetics within the EU.
Safety ProfileModerately toxic by ingestion. A severe skin irritant. See also ALDEHYDES. When heated to decomposition it emits acrid smoke and irritating fumes.
MetabolismSo far as is known, all aromatic aldehydes are metabolized in the animal body by oxidation to the corresponding acids. In some instances, the aldehydes are excreted as glucuronides. Cinnamic aldehyde is oxidized to cinnamic acid which is then degraded to benzoic acid, but ethyl cinnamic aldehyde is oxidized to the corresponding acid and is not further metabolized(Williams, 1959).
alpha-Amylcinnamaldehyde Preparation Products And Raw materials
Raw materialsSodium chloride-->Benzaldehyde-->Castor oil-->Potassium hydroxide solution-->Diphenylamine-->Heptaldehyde-->trans-Cinnamic acid-->ISOAMYL ALCOHOL
Preparation Productsalpha-Hexylcinnamaldehyde
TOSLAB 860369 Cinnamaldehyde 2-PROPENAL, 3-(4-METHYLPHENYL)-,(2E) α-Methylcinnamaldehyde alpha-Hexylcinnamaldehyde alpha-Amylcinnamaldehyde Isoamyl nitrite 1-Nonanal Cyclopentanecarbaldehyde Paraldehyde 2-Chlorophenyl cyclopentyl ketone CYCLOPENTYLMAGNESIUM CHLORIDE TOSLAB 860370 α-Lipoic Acid TERT-AMYL METHYL ETHER cyclamen aldehyde 3-(4-METHYLBENZYLIDENE)CAMPHOR  Diethylstilbestrol

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