2-Bromo-4-methylaniline

2-Bromo-4-methylaniline Basic information

Product Name:	2-Bromo-4-methylaniline
Synonyms:	2-bromo-4-methyl-benzenamin;2-Bromo-4-methylbenzenamine;2-Bromo-4-toluidine;2-bromo-p-toluidin;2-Bromo-4-methylaniline,99% (4-Amino-3-bromtoluol);2-Bromo-p-toluid;4-Amino-3-bromotoluene~2-Bromo-p-toluidine;2-Bromo-4-methylanline
CAS:	583-68-6
MF:	C7H8BrN
MW:	186.05
EINECS:	209-515-7
Product Categories:	Aromatic Hydrocarbons (substituted) & Derivatives;Anilines, Amides & Amines;Bromine Compounds;Amines;blocks;Bromides
Mol File:	583-68-6.mol

2-Bromo-4-methylaniline Chemical Properties

Melting point	14-16 °C (lit.)
Boiling point	240 °C (lit.)
density	1.5 g/mL at 25 °C (lit.)
refractive index	n20/D 1.602(lit.)
Fp	>230 °F
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	Chloroform (Slightly)
form	Oil
pka	2.97±0.10(Predicted)
color	Dark Yellow to Dark Beige
Specific Gravity	1.500
Water Solubility	Insoluble in water.
BRN	1931711
Stability:	Air Sensitive
InChIKey	UVRRJILIXQAAFK-UHFFFAOYSA-N
CAS DataBase Reference	583-68-6(CAS DataBase Reference)
NIST Chemistry Reference	Benzenamine, 2-bromo-4-methyl-(583-68-6)
EPA Substance Registry System	Benzenamine, 2-bromo-4-methyl- (583-68-6)

Safety Information

Hazard Codes	T,Xi,Hazard
Risk Statements	23/24/25-36/37/38-33-20/21/22
Safety Statements	36/37/39-45-26
RIDADR	UN 2810 6.1/PG 3
WGK Germany	3
RTECS	XU4300000
Hazard Note	Irritant/Toxic
TSCA	Yes
HazardClass	6.1
PackingGroup	III
HS Code	29214300

MSDS Information

Provider	Language
4-Amino-3-bromotoluene	English
SigmaAldrich	English
ACROS	English
ALFA	English

2-Bromo-4-methylaniline Usage And Synthesis

Chemical Properties	clear light yellow to brown liquid
Uses	2-Bromo-4-methylaniline has been used in the synthesis of iminophosphoranes.
General Description	2-Bromo-4-methylaniline participates in palladium catalyzed selective amination of 3-bromoquinoline to yield 3-(2-bromo-4-methylphenylamino) quinoline. It reacts with ethyl and methyl imidazo[1,2-a]pyridine-2-carboxylates in the presence of Me₃Al to form amide.

2-Bromo-4-methylaniline Preparation Products And Raw materials

Raw materials	Sodium sulfite-->p-Acetotoluidide-->N-Acetyl-p-toluidine -->Silanamine, 1,1,1-trimethyl-N-(4-methylphenyl)--->methyl N-(2-bromo-4-methylphenyl)carbamate-->2-BROMO-4-METHYLANILINE HYDROCHLORIDE-->2-BroMo-4-Methyl-1-nitro-benzene-->2-Bromo-4-methylphenylboronic acid-->2-BROMO-N-METHYLANILINE 95
Preparation Products	3-Bromotoluene-->2-BROMO-4-METHYLBENZONITRILE-->5-Methylindole-->2-Bromo-4-methylphenol-->2'-BROMO-4'-METHYLACETANILIDE-->5-METHYLINDOLE-3-CARBOXYLIC ACID METHYL ESTER-->5-METHYL-2-PHENYLINDOLE-->2-Chloro-6-methylbenzothiazole-->2-Amino-5-Methyl-Benzonitrile-->2-Bromo-4-methylbenzaldehyde

N-(1-benzofuran-2-ylmethyl)-4-bromo-3-methylaniline 2-Amino-1,3-dibromofluorene 2-BROMO-6-METHYLANILINE 3,3',5,5'-Tetramethylbenzidine dihydrochloride 2-AMINO-3-BROMO-9-FLUORENONE 4-AMINO-3-BROMOBENZOTRIFLUORIDE N-[1-(1,3-benzothiazol-2-yl)ethyl]-4-bromo-3-methylaniline ALTRENOGEST toluidine 2,6-Dibromo-4-ethylaniline 3-bromo-5-methylaniline 2-AMINO-1-BROMO-3-CHLOROANTHRAQUINONE 4-AMINO-3-BROMO-5-NITROBENZOTRIFLUORIDE 2-BROMO-5-METHYLANILINE AMINO ACIDS 4-BROMO-2-METHYLANILINE, BOC PROTECTED 2-BROMO-4-NITROANILINE 2-BROMO-3-METHYLANILINE 98

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