3-Bromothioanisole

3-Bromothioanisole Basic information

Product Name:	3-Bromothioanisole
Synonyms:	3-BROMOPHENYL METHYL SULFIDE;3-BROMOTHIOANISOLE;1-BROMO-3-(METHYLTHIO)BENZENE;M-BROMO(METHYLTHIO)BENZENE;M-BROMOTHIOANISOLE;3-Bromophenyl methyl sulphide, 1-Bromo-3-(methylsulphanyl)benzene, 1-Bromo-3-(methylthio)benzene;Benzene,1-broMo-3-(Methylthio)-;1-bromo-3-methylsulfanylbenzene
CAS:	33733-73-2
MF:	C7H7BrS
MW:	203.1
EINECS:	608-901-6
Product Categories:	Aromatics;Sulfur & Selenium Compounds;Miscellaneous;Aromatics Compounds
Mol File:	33733-73-2.mol

3-Bromothioanisole Chemical Properties

Boiling point	124-125 °C10 mm Hg(lit.)
density	1.51 g/mL at 25 °C(lit.)
refractive index	n20/D 1.628(lit.)
Fp	>230 °F
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	soluble in Chloroform, Ethyl Acetate
form	clear liquid to slightly cloudy liquid
color	Colorless to Yellow
Specific Gravity	1.510
Sensitive	Stench
BRN	2078598
CAS DataBase Reference	33733-73-2(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	23-24/25-37-26
RIDADR	UN 3334
WGK Germany	3
Hazard Note	Irritant/Stench
HazardClass	IRRITANT, STENCH
HS Code	29309090

MSDS Information

Provider	Language
SigmaAldrich	English
ALFA	English

3-Bromothioanisole Usage And Synthesis

Chemical Properties	Pale-Yellow Liquid
Uses	3-Bromothioanisole is a useful reagent for the preparation of (Z)-1,2-diborylalkenes via sodium-metal-promoted reductive 1,2-syn-diboration of alkynes with reduction-??resistant trimethoxyborane.

3-Bromothioanisole Preparation Products And Raw materials

Raw materials	1-bromo-3-[(3-bromophenyl)disulfanyl]benzene-->3-Bromophenylboronic acid-->3-BROMOTHIOPHENOL-->3-(METHYLTHIO)ANILINE-->1-Bromo-3-iodobenzene-->Dimethyl disulfide-->Sodium thiomethoxide-->Dimethyl sulfate-->Iodomethane-->Di-tert-butyl peroxide-->3-Bromofluorobenzene
Preparation Products	3-(Methylthio)benzoic acid-->3-FLUOROTHIOANISOLE

Hydrogen Sulfide Methyl AKOS BBS-00004698 3-Bromothioanisole Bensulfuron methyl 4,4'-Sulphonylbis(2,6-dibromophenol) POLY(1,4-PHENYLENE SULFIDE) Anise oil CARBONYL SULFIDE 2-Thiobarbituric acid 3-(TRIFLUOROMETHYLTHIO)BROMOBENZENE POLY(1,4-PHENYLENE SULFIDE) Kresoxim-methyl Thiophanate-methyl Tetrabromobisphenol A bis(dibromopropyl ether) 4-Methoxyphenol Thioanisole Decabromodiphenyl oxide

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