Diphenylphosphine oxide

Diphenylphosphine oxide Basic information
Product Name:Diphenylphosphine oxide
Synonyms:Diphenylphosphonousacid;Diphenylphosphineoxide,97%;Diphenylphosphine oxide 97%;Two phenylphosphate oxygen;Phosphine oxide,diphenyl-;TIMTEC-BB SBB005946;Diphenylphosphaneoxide;Diphenylphosphinigsαure
CAS:4559-70-0
MF:C12H11OP
MW:202.19
EINECS:625-671-2
Product Categories:Phosphorus Compounds;Phosphorus Precursors;Achiral Phosphine;Aryl Phosphine;Pharmaceutical Intermediates;Catalysis and Inorganic Chemistry
Mol File:4559-70-0.mol
Diphenylphosphine oxide Structure
Diphenylphosphine oxide Chemical Properties
Melting point 56-57 °C(lit.)
Boiling point 102-105°C 0,2mm
refractive index 1.608-1.61
storage temp. Inert atmosphere,Room Temperature
form Crystals
color Yellow to light orange
Water Solubility Slightly soluble in water.
Sensitive Moisture Sensitive
InChIInChI=1S/C12H11OP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,14H
InChIKeyASUOLLHGALPRFK-UHFFFAOYSA-N
SMILESP(=O)(C1=CC=CC=C1)C1=CC=CC=C1
CAS DataBase Reference4559-70-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 22-36/37/38
Safety Statements 26
WGK Germany 2
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Diphenylphosphine oxide Usage And Synthesis
Chemical PropertiesYellow to light orange crystals
UsesUsed in the preparation of triarylphosphine oxides, and as asymmetric catalysts, preparation of alkenyldiphenylphosphine oxides, and Horner-Wittig reagents. It is a ligand for Buchwald-Hartwig Cross Coupling Reaction, Hydrophosphonylations and Suzuki-Miyaura Coupling.
Usessuzuki reaction
DefinitionChEBI: Diphenylphosphine oxide is a member of benzenes.
Synthesis Reference(s)Journal of the American Chemical Society, 45, p. 165, 1923 DOI: 10.1021/ja01654a024
(1-Hydroxy-2-naphtyl)diphenylphosphine oxide (2-Chloro-3,6-dimethoxyphenyl)diphenylphosphine oxide 2-Butyne-1,4-diylbis(diphenylphosphine oxide) [5-(2-Hydroxyethoxy)-2-[2-(2-hydroxyethoxy)ethoxy]phenyl]diphenylphosphine oxide DIPHENYLETHYLPHOSPHINE OXIDE (Diethoxymethyl)diphenylphosphine oxide Iron oxide CIS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE DIOXIDE 1,4-Butanediylbis(diphenylphosphine oxide),Tetramethylenebis(diphenylphosphine oxide) [2,5-Bis[2-(2-hydroxyethoxy)ethoxy]phenyl]diphenylphosphine oxide [2,5-Bis(2-hydroxyethoxy)phenyl]diphenylphosphine oxide Phosphorus oxychloride 1,2-ETHYLENE BIS(DIPHENYLPHOSPHINE OXIDE) (2-Lithio-3,6-dimethoxyphenyl)diphenylphosphine oxide ALLYLDIPHENYLPHOSPHINE OXIDE MALAOXON [3,6-Dimethoxy-2-[(2,3-dimethoxyphenyl)hydroxymethyl]phenyl]diphenylphosphine oxide CYCLOHEXYLDIPHENYLPHOSPHINE OXIDE

Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.