4-Methylthiazole

4-Methylthiazole Basic information
Product Name:4-Methylthiazole
Synonyms:4-methyl-thiazol;Thiazole, 4-methyl-;METHYLTHIAZOLE, 4-;FEMA NUMBER 3716;FEMA 3716;4-METHYLTHIAZOLE;4-METHYL-1,3-THIAZOLE;4-METHYLTHIAZOLE 98+%
CAS:693-95-8
MF:C4H5NS
MW:99.15
EINECS:211-764-1
Product Categories:thiazole Flavor;Thiazoles;Alphabetical Listings;Flavors and Fragrances;Building Blocks;Heterocyclic Building Blocks;M-N;bc0001
Mol File:693-95-8.mol
4-Methylthiazole Structure
4-Methylthiazole Chemical Properties
Melting point 134 °C
Boiling point 133-134 °C (lit.)
density 1.09 g/mL at 25 °C (lit.)
FEMA 3716 | 4-METHYLTHIAZOLE
refractive index n20/D 1.524(lit.)
Fp 90 °F
storage temp. Inert atmosphere,2-8°C
form Liquid
pkapK1:3.16(+1) (25°C,μ=0.1)
color Clear colorless to slightly yellow
Specific Gravity1.090
Odorat 0.10 % in dipropylene glycol. nutty green vegetable tomato
Odor Typenutty
JECFA Number1043
BRN 105228
InChIKeyQMHIMXFNBOYPND-UHFFFAOYSA-N
LogP0.90
CAS DataBase Reference693-95-8(CAS DataBase Reference)
NIST Chemistry Reference4-Methylthiazole(693-95-8)
EPA Substance Registry SystemThiazole, 4-methyl- (693-95-8)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 10-22-37/38-41
Safety Statements 16-26-39
RIDADR UN 1993 3/PG 3
WGK Germany 3
RTECS XJ5096000
TSCA T
HazardClass 3
PackingGroup III
HS Code 29341000
Hazardous Substances Data693-95-8(Hazardous Substances Data)
MSDS Information
ProviderLanguage
4-Methylthiazole English
ACROS English
SigmaAldrich English
ALFA English
4-Methylthiazole Usage And Synthesis
Description4-Methylthiazole has a nutty, green odor.
Chemical Properties4-Methylthiazole has a nutty, green odo
Chemical PropertiesCLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID
OccurrenceReported found in cooked asparagus, roasted barley, cooked beef, cocoa, cooked pork, roasted coffee, roasted peanuts, boiled egg, malt, wort and cooked shrimp.
Uses4-Methylthiazole was used in the synthesis of catalytic dendrophanes, as functional mimics of the thiamine-diphosphate-dependent enzyme pyruvate oxidase. It was used in small scale preparation of 3-butyl-4-methylthiazolium bromide.
DefinitionChEBI: A 1,3-thiazole substituted by a methyl group at position 4.
Taste threshold valuesTaste characteristics at 10 ppm: green, vegetative and meaty with an alliaceous nuance
General Description4-Methylthiazole forms complexes with cobalt(II), zinc(II), nickel(II) and copper(II) halides.
Methylisothiazolinone MTT Methyl Benzothiazole 4-Methylthiazole-5-carboxylic acid Fosthiazate Basic Violet 1 2-Bromo-5-methylthiazole Tribenuron methyl 4-Thiazolecarboxylic acid 4-METHYL-5-THIAZOLEETHANOL (5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLE),4-methylthiazole-5-thiazoleethanol Methylchloroisothiazolinone/methylisothiazolinone mixture (MCIT/MIT) Kresoxim-methyl 2,2'-Dithiobis(benzothiazole) Thiazole Methanol Methyl acrylate METSULFURON METHYL

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