N,N-DIMETHYLPHOSPHORAMIDODICHLORIDATE

N,N-DIMETHYLPHOSPHORAMIDODICHLORIDATE Basic information
Product Name:N,N-DIMETHYLPHOSPHORAMIDODICHLORIDATE
Synonyms:N,N-DIMETHYLPHOSPHORAMIC DICHLORIDE;N,N-DIMETHYLPHOSPHORAMIDIC DICHLORIDE;N,N-DIMETHYLPHOSPHORAMIDODICHLORIDATE;PHOSPHORIC ACID DIMETHYLAMIDE DICHLORIDE;DIMETHYLAMINOPHOSPHORYL DICHLORIDE;DIMETHYLAMINE PHOSPHORYL DICHLORIDE;DIMETHYLAMIDOPHOSPHORIC DICHLORIDE;DMPADC
CAS:677-43-0
MF:C2H6Cl2NOP
MW:161.95
EINECS:211-641-2
Product Categories:
Mol File:677-43-0.mol
N,N-DIMETHYLPHOSPHORAMIDODICHLORIDATE Structure
N,N-DIMETHYLPHOSPHORAMIDODICHLORIDATE Chemical Properties
Boiling point 77-79 °C/11 mmHg (lit.)
density 1.362 g/mL at 20 °C (lit.)
refractive index n20/D 1.464
Fp 89-90°C/20mm
storage temp. 2-8°C
solubility Miscible with dimethoxyethane.
pka-6.60±0.70(Predicted)
form Oil to Semi-Solid
color Colourless to Off-White
Sensitive Moisture Sensitive
BRN 969956
Stability:Hygroscopic, Moisture Sensitive
CAS DataBase Reference677-43-0
EPA Substance Registry SystemN,N-Dimethyl phosphoramidic dichloride (677-43-0)
Safety Information
Hazard Codes C
Risk Statements 34-37
Safety Statements 26-36/37/39
RIDADR UN 3265 8/PG 3
WGK Germany 3
RTECS TB4025000
1-3-10
HazardClass 8
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
N,N-DIMETHYLPHOSPHORAMIDODICHLORIDATE Usage And Synthesis
Chemical PropertiesLight yellow liquid
UsesN,N-Dimethylphosphoramidodichloridate is used in the synthesis of phosphoramidates as well as (RS)-ethyl N,N-dimethylphosphoramidocyanidate (Nerve agent GA) which is used as a chemical weapon. It forms active intermediates, which react with alcohols in situ to give esters. It is also used to convert primary alcohols to alkyl chlorides. Furthe, it serves as an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff. In addition to this, it reacts with 1,2 diols to prepare cyclic phosphoric amides followed by alkenes after reduction.
N,N-DIMETHYLPHOSPHORAMIDODICHLORIDATE Preparation Products And Raw materials
Preparation ProductsDIMEFOX
DI-CHLORO N,N-DIISOPROPYLPHOSPHORAMIDITE N,N-DIMETHYLPHOSPHORAMIDODICHLORIDATE DIMETHYLPHOSPHORAMIDOUS DICHLORIDE AURORA KA-1672 DICHLORO N,N-DIETHYLPHOSPHORAMIDITE N,N-DIMETHYLPHOSPHORAMIDODICHLORIDATE (DIMETHYLAMINOPHOSPHORYL DICHLORIDE; N,N-DIMETHYLPHOSPHORAMIC DICHLORIDE; DMPADC N,N-DIMETHYLPHOSPHORAMIDODICHLORIDATE (DIMETHYLAMINOPHOSPHORYL DICHLORIDE; N,N-DIMETHY

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