1,1,1-TRIMETHYLHYDRAZINIUM IODIDE

1,1,1-TRIMETHYLHYDRAZINIUM IODIDE Basic information
Product Name:1,1,1-TRIMETHYLHYDRAZINIUM IODIDE
Synonyms:1,1,1-TRIMETHYLHYDRAZINIUM IODIDE;1,1,1-TRIMETHYLHYDRAZONIUM IODIDE;1,1,1-trimethyl-hydraziniuiodide;1,1,1-trimethyl-hydrazoniuiodide;1,1,1-triMethylhydrazin-1-iuM iodide;1,1,1-TriMethylhydraziniuM iodide 97%;Mildronate Impurity 1;amino(trimethyl)azanium:iodide
CAS:3288-80-0
MF:C3H11IN2
MW:202.04
EINECS:
Product Categories:Hydrazines;Nitrogen Compounds;Organic Building Blocks
Mol File:3288-80-0.mol
1,1,1-TRIMETHYLHYDRAZINIUM IODIDE Structure
1,1,1-TRIMETHYLHYDRAZINIUM IODIDE Chemical Properties
Melting point 225-230 °C (dec.) (lit.)
EPA Substance Registry System1,1,1-trimethylhydrazinium iodide (3288-80-0)
Safety Information
Hazard Codes T
Risk Statements 61-36/37/38
Safety Statements 53-36/37/39-45
WGK Germany 3
RTECS MW0349100
HS Code 2928009090
MSDS Information
ProviderLanguage
SigmaAldrich English
1,1,1-TRIMETHYLHYDRAZINIUM IODIDE Usage And Synthesis
Uses1,1,1-Trimethylhydrazinium iodide (TMHI) may be employed for the amination of 1-X-3,5-dinitrobenzenes.
General Description1,1,1-Trimethylhydrazinium iodide ([(CH3)3N-NH2]I, TMHI) is widely employed as a vicarious nucleophilic substitution (VNS) reagent for various aromatic amination reactions. On reaction with silver salt, it affords the following salts: nitrate (([(CH3)3N-NH2][NO3]), perchlorate ([(CH3)3N-NH2][ClO4]), azide ([(CH3)3N-NH2][N3]), 5-amino-1H-tetrazolate ([(CH3)3N-NH2][H2N-CN4]) and sulfate ([(CH3)3N-NH2]2[SO4].2H2O).
1,1,1-TRIMETHYLHYDRAZINIUM IODIDE Preparation Products And Raw materials
SALOR-INT L166707-1EA 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE 2-[(DIMETHYLAMINO)METHYLENE]-1,1,1-TRIMETHYLHYDRAZINIUM IODIDE 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE, TECH 2-Hydroxy-3-methoxybenzaldehyde, hyrazone with 1,1,1-trimethylhydrazon ium iodide N-(1-METHYLPYRROLIDIN-1-IUM)-2-[(4,6-DIMETHOXYPYRIMIDIN-2-YL)OXY]BENZAMIDE, IODIDE (2S)-1-METHYL-1-[N-(DIPHENYLMETHYLENE)]-2-HYDROXYMETHYLPYRROLIDINE, HYDRAZONIUM IODIDE

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