3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Basic information
Product Name:3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
Synonyms:3,4-epoxycyclohexanecarboxylicacid(3,4-epoxycyclohexylmethyl)ester;3,4-epoxycyclohexanemethyl3,4-epoxycyclohexanecarboxylate;3,4-epoxycyclohexylmethyl3,4-epoxycyclo-hexaneca;7-oxabicyclo(4.1.0)heptane-3-carboxylicacid,7-oxabicyclo(4.1.0)hept-3-ylmethy;7-Oxabicyclo[4,1,0]heptane-3-carboxylicacid,7-oxabicyclo[4,1,0]hept-3-ylmethylester;3,4-Epoxycyclohexylmethyl-3,4-epoxycy-clohexane Carboxylate (JR-HS-21);7-Oxabicyclo[4.1.0]heptan-3-ylmethyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate;1,2-Epoxycyclohexane-4-carboxylic acid 1,2-epoxycyclohexane-4-ylmethyl ester
CAS:2386-87-0
MF:C14H20O4
MW:252.31
EINECS:219-207-4
Product Categories:Epoxide Monomers;Monomers;Polymer Science
Mol File:2386-87-0.mol
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Structure
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Chemical Properties
Melting point −37 °C(lit.)
Boiling point 355.49°C (rough estimate)
density 1.17 g/mL at 25 °C(lit.)
vapor pressure 0.002Pa at 25℃
refractive index n20/D 1.498(lit.)
Fp 245 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), Dichloromethane (Slightly)
pka4.61±0.20(Predicted)
form Oil
color Colourless
Specific Gravity1.170
Water Solubility 13.85g/L at 20.2℃
InChIKeyNHJIDZUQMHKGRE-UHFFFAOYSA-N
LogP1.34 at 20℃
CAS DataBase Reference2386-87-0(CAS DataBase Reference)
EPA Substance Registry System7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 7-oxabicyclo[4.1.0]hept-3-ylmethyl ester (2386-87-0)
Safety Information
Hazard Codes Xi
Risk Statements 43
Safety Statements 36/37
WGK Germany 1
RTECS RN7750000
HS Code 29189900
Hazardous Substances Data2386-87-0(Hazardous Substances Data)
ToxicityLD50 oral in rat: 4490mg/kg
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Usage And Synthesis
Chemical PropertiesPale yellow to colorless transparent liquid
UsesEEC is an epoxy monomer that can be used as a resin in aerospace, electronics and automobile industries as an adhesive and a composite material.
UsesThis compound can be made by treatment of the corresponding bis-unsaturated ester with peracetic acid. It is used as a reactive diluent, for filament winding, as an acid scavenger, or as a plasticizer. Vapor hazard is slight at ambient temperature because of its moderately high boiling point. Skin contact is to be avoided.
General Description3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate (EEC) is a cycloaliphatic epoxy that can be synthesized by the reaction of 3′-cyclohexenylmethyl 3-cyclohexenecarboxylate with peracetic acid. Its aliphatic backbone and molecular structure provide a number of useful properties such as thermal stability, weatherability, and electrical conductivity.
Flammability and ExplosibilityNonflammable
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Preparation Products And Raw materials
Raw materials3-Cyclohexenyl 3-cyclohexene 1-carboxylate
BIS(3,4-EPOXYCYCLOHEXYLMETHYL) ADIPATE 1,2-Epoxy-4-vinylcyclohexane Dicyclopentadiene diepoxide methylbenzoic acid Cyclohexanecarboxylic acid CYCLOHEXYL ISOVALERATE ETHYL CYCLOHEXYLACETATE 2-(Trifluoromethyl)benzoic acid m-Toluic acid 4-(Chloromethyl)benzoic acid o-Toluic acid 3-Ethyl-7-oxabicyclo(4.1.0)heptane Cyclohexylacetic acid METHYLCYCLOHEXANOL p-Toluic acid propyl cyclohexaneacetate METHYL CYCLOHEXANEACETATE 2-Methyl-2-propenoic acid cyclohexyl ester

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