Rhodium carbonyl chloride

Rhodium carbonyl chloride Basic information

Product Name:	Rhodium carbonyl chloride
Synonyms:	Dirhodium tetracarbonyl dichloride;Di-μ-chloro-tetracarbonyldirhodium(I), Rhodium carbonyl chloride(I), Rhodium(I) carbonyl chloride, Rhodium(I) dicarbonyl chloride dimer, Tetracarbonyldi-μ-chlorodirhodium(I);Rhodium carbonyl chloride(I), Rhodium(I) carbonyl chloride, Rhodium(I) dicarbonyl chloride dimer, Tetracarbonyldi-μ-chlorodirhodium(I);Tetracarbonyldi--chlorodirhodium(I);TETRACARBONYLDI-MU-CHLORODIRHODIUM(I);TETRACARBONYLDI-U-CHLORODIRHODIUM(I);BIS(CHLORODICARBONYL)RHODIUM;DI-MU-CHLORO-TETRACARBONYLDIRHODIUM
CAS:	14523-22-9
MF:	4CO.Cl2Rh2
MW:	388.77
EINECS:	238-540-6
Product Categories:	metal carbonyl complexes;Rh;Metal Compounds
Mol File:	14523-22-9.mol

Rhodium carbonyl chloride Chemical Properties

Melting point	120-125 °C (dec.)(lit.)
storage temp.	2-8°C
solubility	It is soluble in organic or non-aqueous solvent.
form	crystal
color	red
Water Solubility	soluble in most organic solvents; insoluble aliphatic hydrocarbons [MER06]
Sensitive	Air & Moisture Sensitive
Merck	14,8187
Exposure limits	ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference	14523-22-9(CAS DataBase Reference)
NIST Chemistry Reference	Dirhodium tetracarbonyl dichloride(14523-22-9)

Safety Information

MSDS Information

Rhodium carbonyl chloride Usage And Synthesis

Reaction	Catalyst used for a wide range of cycloadditions reactions.
Chemical Properties	red to brownish crystals, crystalline powder or
Uses	Catalyst for organic reactions.
Uses	Rhodium Carbonyl Chloride is a reagent for rhodium-catalyzed [4+2+1] cycloaddition of in situ generated ene/yne-ene-allenes and carbon monoxide to produce [4+2+1] cycloadducts

Rhodium carbonyl chloride Preparation Products And Raw materials

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