1-PROPYNYLMAGNESIUM BROMIDE

1-PROPYNYLMAGNESIUM BROMIDE Basic information
Product Name:1-PROPYNYLMAGNESIUM BROMIDE
Synonyms:1-PROPYNYLMAGNESIUM BROMIDE;1-PROPYNYLMAGNESIUM BROMIDE SOLUTION, ~0 .5 M IN THF;1-PROPYNYLMAGNESIUM BROMIDE, 0.5M SOLUTI ON IN TETRAHYDROFURAN;1-Propynylmagnesium bromide, 0.5M solution in THF, AcroSeal;(1-Propynyl)bromomagnesium;1-Propynylbromomagnesium;Bromo(1-propynyl) magnesium;1-Propynylmagnesium bromide,0.5M solution inTHF
CAS:16466-97-0
MF:C3H3BrMg
MW:143.26
EINECS:
Product Categories:Grignard Reagent;Chemical Synthesis;Grignard Reagents;Organometallic Reagents;Alkynyl;Grignard Reagents;Organometallic Reagents
Mol File:16466-97-0.mol
1-PROPYNYLMAGNESIUM BROMIDE Structure
1-PROPYNYLMAGNESIUM BROMIDE Chemical Properties
Melting point 53.5 °C(Solv: methanol (67-56-1))
Boiling point 65-67 °C
density 0.941 g/mL at 25 °C
Fp <−30 °F
storage temp. 2-8°C
solubility THF
form Pale Yellow Solution
BRN 3929146
Stability:Moisture Sensitive, Pyrophoric
InChIKeyYVJBCTFVENNIOV-UHFFFAOYSA-M
CAS DataBase Reference16466-97-0
Safety Information
Hazard Codes F,C
Risk Statements 11-14/15-34-40-37-19
Safety Statements 16-26-36/37/39-43-45
RIDADR UN 3399 4.3/PG 1
WGK Germany 1
1-10
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
1-PROPYNYLMAGNESIUM BROMIDE Usage And Synthesis
UsesPreparation of hydroxy enynes which underwent gold(I)-catalyzed benzannulation leading to tetrahydronaphthalenes.1
Uses1-Propynylmagnesium Bromide Solution is a useful research reagent for chemical and organic transformations. It acts as a reagent in the synthesis of lasonolides a novel polyketides with biological activity in vitro against a variety of cancer cell lines.
1-PROPYNYLMAGNESIUM BROMIDE Preparation Products And Raw materials
2-BUTENYLMAGNESIUM CHLORIDE ALLYLMAGNESIUM BROMIDE Hexylmagnesium chloride 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE 1-PROPENYLMAGNESIUM BROMIDE ISOBUTYLMAGNESIUM BROMIDE 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex 2,5-DIMETHYLPHENYLMAGNESIUM BROMIDE 1-METHYL-1-PROPENYLMAGNESIUM BROMIDE ISOPROPENYLMAGNESIUM BROMIDE SEC-BUTYLMAGNESIUM BROMIDE CYCLOPENTYLMAGNESIUM BROMIDE Cyclopropylmagnesium bromide 3-Methoxy-1-propynylmagnesium bromide 1-PROPYNYLMAGNESIUM BROMIDE ETHYNYLMAGNESIUM BROMIDE Methylmagnesium Bromide PHENYLETHYNYLMAGNESIUM BROMIDE

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