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Piperonylonitrile

Piperonylonitrile Basic information
Product Name:Piperonylonitrile
Synonyms:5-Cyano-1,3-benzodioxole;AKOS B004105;AKOS 214-97;1,3-BENZODIOXOLE-5-CARBONITRILE;PIPERONITRILE;PIPERONYLNITRILE;PIPERONYLONITRILE;Piperonylonitrile, 97% 25GR
CAS:4421-09-4
MF:C8H5NO2
MW:147.13
EINECS:224-590-6
Product Categories:Benzodiozoles, Benzodioxines & Benzodioxepines;Benzodiozoles, Benzodioxines & Benzodioxepines;Aromatic Esters
Mol File:4421-09-4.mol
Piperonylonitrile Structure
Piperonylonitrile Chemical Properties
Melting point 91-93 °C (lit.)
Boiling point 267.22°C (rough estimate)
density 1.3067 (rough estimate)
refractive index 1.5510 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility Dichloromethane, Ethyl Acetate, Methanol
form Crystalline Powder or Needles
color White to beige
BRN 6224
InChIKeyPKRWWZCDLJSJIF-UHFFFAOYSA-N
CAS DataBase Reference4421-09-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 20/21/22-20/21
Safety Statements 36-23-24/25
RIDADR 3276
WGK Germany 3
RTECS TO2645000
Hazard Note Irritant
HazardClass 6.1
PackingGroup III
HS Code 29329990
Toxicitymouse,LD50,intravenous,18mg/kg (18mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#04711,
MSDS Information
ProviderLanguage
3,4-(Methylenedioxy)benzonitrile English
SigmaAldrich English
ACROS English
ALFA English
Piperonylonitrile Usage And Synthesis
Chemical Propertieswhite to beige crystalline powder or needles
UsesPiperonylonitrile has been used to alter the growth of Nif + and Nif - strains of K.pneumoniae.
UsesA methylenedioxyphenyl (MDP) compound. Inhibitor of nasal P 450-dependent N-demethylase in rabbits. Toxic against D. farinae, D. pteronyssinus, and T. putrescentiae.
DefinitionChEBI: Piperonylonitrile is a member of benzodioxoles.
Piperonylonitrile Preparation Products And Raw materials
Preparation ProductsPiperonylic acid-->1,3-BENZODIOXOLE-5-CARBOTHIOAMIDE-->(+/-)-1-(1,3-Benzodioxol-5-yl)-2-broMo-1-pentanone-->1-(benzo[d][1,3]dioxol-5-yl)cyclopropanamine-->4-[3-(1,3-BENZODIOXOL-5-YL)-1,2,4-OXADIAZOL-5-YL]PIPERIDINE -->1-(benzo[d][1,3]dioxol-5-yl)pentan-1-one
Piperonylonitrile 4-Nitrobenzonitrile Black Pepper Oil 6-NITRO-1,3-BENZODIOXOLE-5-CARBONITRILE 5-CYANO-2,2-DIFLUORO-1,3-BENZODIOXOLE 1,3-Benzodioxole 6-BROMO-1,3-BENZODIOXOLE-5-CARBONITRILE Anisole (Trifluoromethoxy)benzene 1,3-BENZODIOXOLE-5-CARBONITRILE, 6-(1H-PYRROL-1-YL)- Benzonitrile p-Tolunitrile 6-AMINO-1,3-BENZODIOXOL-5-YL CYANIDE 2-Cyanophenol PIPERONYLONITRILE, (3,4-METHYLENEDIOXYBENZONITRILE)
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