(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE

(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE Basic information
Reaction
Product Name:(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE
Synonyms:(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE;(S,S)-(+)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane(1,5-cyclooctadiene)rhodium(I) terafluoroborate;(S,S)-(+)-1,2-Bis[(o-Methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodiuM(I)tetrafluoroborate,Min.95%;(S,S)-(+)-1,2-Bis[(o-Methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,95%;[(S,S)-1,2-Ethanediyl-bis-[(2-methoxyphenyl)-phenylphosphine]]-(1,5-cyclooctadiene)-rhodium(Ⅰ)]-tetrafluoroborate;(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)
rhodium(I) tetrafluoroborate, min. 95%
;(S,S)-(+)-1,2-Bis[(o-Methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate;(1S,2S)-()-Bis[(2-methoxyphenyl)phenylphosphino]ethane -(1,5-cyclooctadiene) rhodium(I) tetrafluorobarate
CAS:71423-54-6
MF:C36H38BF4O2P2Rh
MW:754.35
EINECS:
Product Categories:Rh;organometallic complex
Mol File:71423-54-6.mol
(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE Structure
(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE Chemical Properties
form Powder
color orange
Sensitive air sensitive
CAS DataBase Reference71423-54-6
Safety Information
Safety Statements 22-24/25
HS Code 28439000
MSDS Information
(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE Usage And Synthesis
Reaction
  1. Highly reactive enantioselective catalyst for the asymmetric hydrogenation of various substituted dehydroalanines to Nprotected aminoacids. Also, catalyst is very effective in the asymmetric reduction of pentapetides that contain unsaturated Phe or Tyr linkages to enkephalin, a brain peptide hormone.
  2. Efficient catalyst for the asymmetric reduction of enol acetates to esters.
  3. Catalyst used to prepare chiral 2-substituted succinic acid derivatives.
Reactions of 71423-54-6
(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE Preparation Products And Raw materials
(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE BIS(2-METHOXYPHENYL)PHENYLPHOSPHINE

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