BATHOPHENANTHROLINEDISULFONIC ACID DISODIUM SALT TRIHYDRATE

BATHOPHENANTHROLINEDISULFONIC ACID DISODIUM SALT TRIHYDRATE Basic information
Product Name:BATHOPHENANTHROLINEDISULFONIC ACID DISODIUM SALT TRIHYDRATE
Synonyms:Bathophenanthrolinedisulfonic acid trihydrate disodium salt, Disodium bathophenanthrolinedisulfonate trihydrate, 4,7-Diphenyl-1,10-phenanthroline-disulfonic acid trihydrate disodium salt;Bathophenanthrolinedisulfonic acid disodium salt trihydrote;BATHOPHENANTHROLINEDISULFONIC ACID DISODIUM SALT;BATHOPHENANTHROLINEDISULFONIC ACID DISODIUM SALT TRIHYDRATE;BATHOPHENANTHROLINE-DISULFONIC ACID SODIUM SALT;BATHOPHENANTHROLINEDISULPHONIC ACID DISODIUM SALT;BATHOPHENANTHROLINE SULFONATE;Bathophenanthrolinedisulfonic acid trihydrate disodium salt
CAS:52746-49-3
MF:C24H14N2O6S2.2Na
MW:536.5
EINECS:258-152-0
Product Categories:Analytical Chemistry;Chelating Reagents;Environmentally-friendly Oxidation;Ligands (Environmentally-friendly Oxidation);Phenanthrolines;Synthetic Organic Chemistry;Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfonic/Sulfinic Acids;Sulfur Compounds
Mol File:52746-49-3.mol
BATHOPHENANTHROLINEDISULFONIC ACID DISODIUM SALT TRIHYDRATE Structure
BATHOPHENANTHROLINEDISULFONIC ACID DISODIUM SALT TRIHYDRATE Chemical Properties
Melting point 300 °C
solubility H2O: soluble
form Powder
color Slightly pinkish-beige
Water Solubility Soluble in water.
CAS DataBase Reference52746-49-3(CAS DataBase Reference)
EPA Substance Registry System1,10-Phenanthrolinedisulfonic acid, 4,7-diphenyl-, disodium salt (52746-49-3)
Safety Information
Hazard Codes Xi
Risk Statements 21/22-36/37/38
Safety Statements 22-24/25-36/37/39-26
WGK Germany 3
RTECS SF8433000
8-10
TSCA Yes
HS Code 29339900
MSDS Information
ProviderLanguage
ALFA English
BATHOPHENANTHROLINEDISULFONIC ACID DISODIUM SALT TRIHYDRATE Usage And Synthesis
Chemical Propertiesslightly pinkish-beige powder
UsesBathophenanthrolinedisulfonic acid disodium salt trihydrate was used in double electrochemical covalent coupling method for the fabrication of sensitive amperometric immunosensor, which was based on electro-click chemistry and diazonium chemistry. It was also used in an experimental study based upon, correlating the iron content with the activity, preparation and reconstituting the apoenzyme phenylamine hydroxylase.
UsesBathophenanthrolinedisulfonic acid disodium salt hydrate has been used to measure iron to determine the solubility of iron in the biological sample. It has been used as an iron chelator to grow plants without Fe-EDTA (ethylenediaminetetraacetic acid).
DefinitionChEBI: An organic sodium salt having 4,7-diphenyl-1,10-phenanthroline 4',4''-disulfonate as the counterion.
General DescriptionBathophenanthrolinedisulfonic acid disodium salt forms water soluble complexes with palladium and their catalytic role in oxidation of 2-hexanol has been examined.
Biochem/physiol ActionsBathophenanthrolinedisulfonic acid is a metal chelator. It permits iron determination to be made in aqueous medium without need for solvent extraction. It forms a complex with Fe2+ and makes it unavailable to Fe2+ transporter, thereby inhibiting the transport of iron into chloroplasts. Bathophenanthrolinedisulfonic acid is also used in the assay for determining intracellular glutathione.
Purification MethodsDissolve crude sample in the minimum volume of water and add EtOH to precipitate the contaminants. Carefully evaporate the filtrate to obtain pure material. It forms a dark red complex with Fe2+ with 535nm ( 2.23 x 104mol-cm -1) [Imasaka et al. Anal Chim Acta 115 407 1980]. It is prepared by sulfonating bathophenanthroline with ClSO3H: to 100g of bathophenanthroline is added 0.5mL of Fe free ClSO3H and heated over a flame for 30seconds. Cool and carefully add 10mL of pure distilled H2O and warm on a water bath with stirring till all solid dissolves. A stock solution is made by diluting 3mL of this reagent to 100mL with 45% aqueous NaOAc, filter off the solid and store in a dark bottle. In this way it is stable for several months. [Landers & Bennie Am J Clinical Pathology 29 590 1958.]
BATHOPHENANTHROLINEDISULFONIC ACID DISODIUM SALT TRIHYDRATE Preparation Products And Raw materials
Sodium acetate trihydrate Silver sulfate Sodium gualenate BATHOPHENANTHROLINEDISULFONIC ACID DISODIUM SALT TRIHYDRATE Bathophenanthroline BATHOCUPROINEDISULFONIC ACID DISODIUM SALT BATHOPHENANTHROLINEDISULFONIC ACID DISODIUM SALT TRIHYDRATE 90+%,BATHOPHENANTHROLINE DISULFONIC ACID NA2-SALT H20,Bathophenanthroline disulfonic acid-Na2-salt

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