(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE)

(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) Basic information
Product Name:(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE)
Synonyms:(R)-(+)-2,2'-ISOPROPYLIDENEBIS(4-PHENYL-2-OXAZOLINE);(R,R)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE;(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE);(R,R)-2,2'-ISOPROPYLIDENEBIS(4-PHENYL-2-OXAZOLINE);(R,R)-2,2μ-Isopropylidenebis(4-phenyl-2-oxazoline), (R,R)-2,2μ-Bis(4-phenyl-2-oxazolin-2-yl)propane;(+)-2,2'-isopropylidenebis[(4r)-4-phenyl-2-oxazoline];(+)-2,2'-isopropylidenebis[(4r)-4-phenyl-2-oxazo;(R,R)-2,2'-(Dimethylmethylene)Bis(4-Phenyl-2-Oxazoline),96%
CAS:150529-93-4
MF:C21H22N2O2
MW:334.41
EINECS:
Product Categories:Chiral Nitrogen;BOX series;Asymmetric Synthesis;Synthetic Organic Chemistry
Mol File:150529-93-4.mol
(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) Structure
(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) Chemical Properties
Melting point 56-58 °C(lit.)
Boiling point 468.9±45.0 °C(Predicted)
density 1.18±0.1 g/cm3(Predicted)
refractive index 160 ° (C=1, EtOH)
storage temp. -20°C
form clear liquid
pka4.85±0.70(Predicted)
color Light yellow to Amber to Dark green
optical activity[α]20/D +160°, c = 1 in ethanol
BRN 4266906
CAS DataBase Reference150529-93-4
Safety Information
Hazard Codes T
Risk Statements 23/24/25
Safety Statements 26-36-45
RIDADR UN 2811 6.1/PG 3
WGK Germany 3
HS Code 29349990
MSDS Information
ProviderLanguage
SigmaAldrich English
(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) Usage And Synthesis
Chemical PropertiesLow melting solid or liquid
Uses(+)-2,2′-Isopropylidenebis[(4R)-4-phenyl-2-oxazoline] in the presence of copper iodide, can catalyze the asymmetric cyclopropanation reaction of phenyliodonium ylides with alkenes to form cyclopropane α-amino acid esters.
(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) Preparation Products And Raw materials
(4R,4'R)-2,2'-(Cyclopentane-1,1-diyl)-bis(4-phenyl-4,5-dihydrooxazole) (4S 4'S)-(-)-2 2'-(3-PENTYLIDENE)BIS(4-& N-BENZYLCINCHONINIUM CHLORIDE (4S,4'S)-2,2'-(Cyclopentane-1,1-diyl)-bis(4-isopropyl-4,5-dihydrooxazole) (1S,2S)-(+)-N,N-Dimethylcyclohexane-1,2-diamine (1S,2S)-N,N'-Dimethyl-1,2-cyclohexanediamine (4S,4'S)- 2,2'-(1-ethylpropylidene)bis[4,5-dihydro-4-phenyl-Oxazole (R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) (S,S)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) 2-(1-(HYDROXYMETHYL)ETHYL)-OXAZOLINE& 2-Ethyl-2-oxazoline 2-ISOPROPYL-2-OXAZOLINE Oxazoline (R)-(-)-1-AMINO-1-PHENYL-2-METHOXYETHANE (R,R)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)

Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.