Direct Black 38

Direct Black 38 Basic information
Product Name:Direct Black 38
Synonyms:chloramineblackert;chloramineblackex;chloramineblackexr;chloramineblackxo;chloraminecarbonblacks;chloraminecarbonblacksj;chloraminecarbonblacksn;CHLORAZOL BLACK, FOR MICROSCOPY
CAS:1937-37-7
MF:C34H28N9NaO7S2
MW:761.76
EINECS:217-710-3
Product Categories:Dyes and Pigments;Organics
Mol File:1937-37-7.mol
Direct Black 38 Structure
Direct Black 38 Chemical Properties
Melting point 109-110°C
storage temp. Amber Vial, Refrigerator, Under inert atmosphere
solubility DMSO (Slightly), Methanol (Slightly, Heated), Water (Slightly)
form Crystalline Powder
Colour Index 30235
color Black
Stability:Light Sensitive
CAS DataBase Reference1937-37-7(CAS DataBase Reference)
EPA Substance Registry SystemC.I. Direct Black 38 (1937-37-7)
Safety Information
Hazard Codes T
Risk Statements 45-63-36
Safety Statements 53-45-36/37-26
WGK Germany 3
RTECS QJ6160000
TSCA Yes
HS Code 29299090
Hazardous Substances Data1937-37-7(Hazardous Substances Data)
ToxicityLD50 orl-rat: 7600 mg/kg TSCAT* OTS 215154
MSDS Information
ProviderLanguage
Chlorazol Black E English
SigmaAldrich English
ACROS English
ALFA English
Direct Black 38 Usage And Synthesis
Chemical Propertiesblack crystalline powder
UsesChlorozol Black E is a chitin-specific stain and used to detect fungal filaments. Dyes and metabolites, Environmental Testing.Environmental toxin on US EPA Toxic Release Inventory list (TRI) list.
Preparation4-(4-Aminophenyl)benzenamine double nitriding, in acid conditions and 4-Amino-5-hydroxynaphthalene-2,7-disulfonic acid?coupling, aniline diazo, in alkaline conditions and 4-Amino-5-hydroxynaphthalene-2,7-disulfonic acid?group of adjacent a coupling, product again with Benzene-1,3-diamine coupling.
General DescriptionGray-black microcrystals or black powder.
Air & Water ReactionsAzo dyes can be explosive when suspended in air at specific concentrations. Slightly soluble in water.
Reactivity ProfileDirect Black 38 is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases may form with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases form with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. Incompatible with strong acids [NTP, 1992)].
HazardConfirmed carcinogen. Moderately toxic by ingestion and inhalation. An eye irritant.
Health HazardACUTE/CHRONIC HAZARDS: Direct Black 38 may be absorbed through the skin. When heated to decomposition it emits very toxic fumes of nitrogen oxides, disodium oxide and sulfur oxides.
Fire HazardFlash point data for Direct Black 38 are not available; however, Direct Black 38 is probably combustible.
Safety ProfileConfirmed carcinogen with carcinogenic and tumorigenic data. Moderately toxic by ingestion and inhalation. An eye irritant. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx, Na2o, and so2.
Properties and Applicationsblack. Palm black powder. Soluble in water for green light black, solubility 40 g/l (85 ℃), and adequate soluble in alcohol for green light blue-black, right amount soluble in soluble fiber element, insoluble in other organic solvents. The strong sulfuric acid is a deep red in blue, diluted Purple dark reddish brown for to red light black precipitation; In nitric acid solution for yellow brown (not completely); In strong hydrochloric acid for dark red light black solution (don’t). The dye solution to join strong hydrochloric acid for Purple dark reddish brown, precipitation; Concentrated sodium hydroxide solution is generated gray light blue precipitaten. Cellulose fiber of dyeing, the dye absorption rate as well, in 80 ℃ temperature when the biggest affinity. Can discharge. Used for cotton, viscose, silk, polyamide fiber and its blending fabric, leather, wood, biological and plastic color, also used as the raw material of black ink.
Standard Acid Resistance Alkali Resistance Light Fastness Soaping Water
Fading Stain Fading Stain
ISO 3 3 3 2 2-3
AATCC 3 3 4-5 3 2
Direct Black 168 Direct Black 38 DIRECT BLACK 22 1-Naphthol-3,6-disulfonic acid disodium salt 3-AMINO-2,7-NAPHTHALENEDISULFONIC ACID MONOSODIUM SALT DIRECT BLACK ALTRENOGEST Black 6-Aminocaproic acid Glycine BLACKEYEDPEAS Direct Tris(hydroxymethyl)aminomethane Ethylenediaminetetraacetic acid disodium salt CHLORAZOL BLACK LF AMINO ACIDS AZOFUCHSIN Carbon

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