ETHYL 2-(BROMOMETHYL)ACRYLATE

ETHYL 2-(BROMOMETHYL)ACRYLATE Basic information

Product Name:	ETHYL 2-(BROMOMETHYL)ACRYLATE
Synonyms:	2-Propenoic acid, 2-(bromomethyl)-, ethyl ester;2-(Bromomethyl)-2-propenoic Acid Ethyl Ester;2-Carbethoxyallyl Bromide;Ethyl 2-(Bromomethyl)-2-propenoate;Ethyl 3-Bromo-2-(methylene)propanoate;NSC 215252;Ethyl 2-(bromomethyl)acrylate,97%;Ethyl 2-(bromomethyl)acrylate ,98%
CAS:	17435-72-2
MF:	C6H9BrO2
MW:	193.04
EINECS:	628-033-1
Product Categories:	Benzothiophenes ,Thiophenes;Aliphatics;AcrylateCarbonyl Compounds;Acrylic Monomers;C6 to C7;Esters;Monomers;All Aliphatics
Mol File:	17435-72-2.mol

ETHYL 2-(BROMOMETHYL)ACRYLATE Chemical Properties

Melting point	134-136℃
Boiling point	38 °C/0.8 mmHg (lit.)
density	1.398 g/mL at 25 °C (lit.)
refractive index	n20/D 1.479(lit.)
Fp	178 °F
storage temp.	-20°C
solubility	Chloroform (Sparingly), Ethyl Acetate (Slightly)
form	Liquid
color	Colorless to pale yellow
BRN	970108
InChIKey	MTCMFVTVXAOHNQ-UHFFFAOYSA-N
CAS DataBase Reference	17435-72-2(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
RIDADR	UN 2810 6.1 / PGII
WGK Germany	3
F	10-19-23
HS Code	29161900

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English

ETHYL 2-(BROMOMETHYL)ACRYLATE Usage And Synthesis

Chemical Properties	Colourless Oil
Uses	ETHYL 2-(BROMOMETHYL)ACRYLATE is an intermediate used for the synthesis of aza inhibitors of chorismate mutase.
Uses	It can be employed as an electrophile for various organometallic compounds. The organometallic derivatives of the compound can be used for the synthesis of α-methylene lactones and lactams. It can also be used for the polymerization of functionalized acrylic monomers.
General Description	Ethyl 2-(bromomethyl)acrylate is an allylic alkylating reagent.
Purification Methods	If it contains some free acid, add H2O, cool, and neutralise with NaHCO3 until evolution of CO2 ceases. Extract the mixture with Et2O (3x) and dry the combined extracts (Na2SO4, 3hours). Evaporate Et2O and distil the ester collecting fraction b 39-40o/0.9mm and check spectra. [Preparation and NMR: Ramarajan et al. Org Synth Coll Vol VII 211 1990, Beilstein 2 IV 1541.]

ETHYL 2-(BROMOMETHYL)ACRYLATE Preparation Products And Raw materials

Raw materials	Ethyl acetate-->Diethyl ether-->PETROLEUM ETHER-->Magnesium sulfate-->Sodium chloride-->Sodium bicarbonate-->1,4-Dioxane-->Formaldehyde-->Phosphorus tribromide-->tert-Butyl methyl ether-->Ethyl acrylate-->Triethylenediamine-->2-(BROMOMETHYL)ACRYLIC ACID-->Ethyl 3-bromo-2-(bromomethyl)propionate-->Ethyl 2-(hydroxymethyl)acrylate-->ETHYLENE-->Diethyl malonate
Preparation Products	2-(CHLOROMETHYL)ACRYLIC ACID ETHYL ESTER

ETHYL 2-OXAZOLECARBOXYLATE ETHYL 2,3,4-TRI-O-BENZYL-1-THIO-BETA-L-FUCOPYRANOSIDE Ethyl 6-oxohexanoate ethyl 6-(trifluoromethyl)tetrahydro-2H-pyran-3-carboxylate ETHYL 2,3-EPOXYPROPANOATE ethyl 2-((ethoxycarbonyl)amino)-4-methyl-5-(4-nitrophenyl)thiophene-3-carboxylate 2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER Ethyl 2-(hydroxymethyl)acrylate 3-Bromo-2-methylpropene ETHYL 2-(BROMOMETHYL)ACRYLATE 3-Bromo-1-propanol Methyl 2-(bromomethyl)acrylate 3-Bromopropionic acid Allyl bromide 1-BROMO-3-ETHOXYPROPANE 2-(BROMOMETHYL)ACRYLIC ACID Methyl 3-bromopropionate Ethyl methacrylate

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