ChemicalBook Product Catalog Organic Chemistry Phosphines (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Basic information
Reactions
Product Name:(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
Synonyms:(R,R)-TROST LIGAND(NAPHTHYL);(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(R,R)-DACH-NaphthylTrostLigand;(R,R)-DACH-naphthyl Trost ligand;(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL);(1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94%;(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (R,R)-DACH-Naphthyl Trost Ligand;(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(R,R)-DACH-Naphthyl Trost Ligand;N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide)
CAS:174810-09-4
MF:C52H44N2O2P2
MW:790.87
EINECS:
Product Categories:Chiral Nitrogen;DACH&Trost Series
Mol File:174810-09-4.mol
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Structure
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Chemical Properties
Melting point 224-231 °C
alpha 69o (C=1 IN METHANOL)
form Powder
pka13.43±0.40(Predicted)
color off-white
optical activity[α]20/D +69.0°, c = 1 in methanol
InChIKeyVXFKMKXTPXVEMU-AWSIMMLFSA-N
CAS DataBase Reference174810-09-4
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
HS Code 2931499090
MSDS Information
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Usage And Synthesis
ReactionsThe palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and fluorides nucleophiles. Reactions of 174810-09-4_1
Reactions of 174810-09-4_2
Chemical Propertieswhite to off-white powder
UsesTrost Ligands for Asymmetric Allylic Alkylation
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Preparation Products And Raw materials
Raw materials2-DIPHENYLPHOSPHINO-1-NAPHTHOIC ACID-->Methyl 2-diphenylphosphino-1-n-->METHYL 2-HYDROXY-1-NAPHTHOATE-->METHYL 2-TRIFLUOROMETHANESULFONYLOXY-1-NAPHTHOATE-->(1R,2R)-(-)-1,2-Diaminocyclohexane
(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1R,2R)-(+)-1,2-Diphenylethylenediamine (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) 2-Diphenylphosphinobenzaldehyde Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine N,N'-Dimethyl-1,2-cyclohexanediamine 1,2-Diaminocyclohexane TRANS-N,N'-DIACETYLCYCLOHEXANE-1,2-DIAMINE
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