ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organonickel BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL

BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL

BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Basic information
Product Name:BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
Synonyms:NICKEL-BIS(TRIPHENYLPHOSPHINE) DICARBONYL;BIS(TRIPHENYLPHOSPHINE)NICKEL DICARBONYL;BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL;DICARBONYL-BIS(TRIPHENYLPHOSPHINE)NICKEL;BIS(TRIPHENYLPHOSPHINE)NICKEL &;Bis(triphenylphosphine)nickel(0)dicarbonyl;Bis(triphenylphosphine)nickeldicarbonyl,98%;Nickel, dicarbonylbis(triphenylphosphine)-, (T-4)-
CAS:13007-90-4
MF:C38H30NiO2P2
MW:639.28
EINECS:235-851-9
Product Categories:metal carbonyl complexes
Mol File:13007-90-4.mol
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Structure
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Chemical Properties
Melting point 206-209 °C (lit.)
storage temp. 2-8°C
form crystal
color light yellow
Sensitive air sensitive
Merck 14,1304
Exposure limitsNIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference13007-90-4
Safety Information
Hazard Codes T
Risk Statements 45-42/43
Safety Statements 53-22-36/37-45
RIDADR 3281
WGK Germany 3
HazardClass 6.1
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Usage And Synthesis
Chemical Propertieslight yellow crystals or crystalline powder
UsesCatalyst in polymerization of acetylene to benzene and styrene, trimerization of ethynyl Compounds, cyclization of butadiene.
UsesCatalyst for:
  • Cyclotrimerization reactions
  • Cyclooligomerization reactions
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Preparation Products And Raw materials
Raw materialsTetrakis(triphenylphosphine)nickel-->Triphenylphosphine-->Nickel-->ZINC
Preparation ProductsNICKELOCENE-->Acetyl ketene
Bis(tricyclohexylphosphine)nickel(II) chloride, 99% [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Bis(tri-tert-butylphosphine)palladium(0) Bis-(triphenylphosphino)-cuprous borohydride Bis(triphenylphosphine)nickel(II)chloride BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE DME Bis(triphenylphosphine)palladium(II) chloride BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Diphenylphosphine CARBON MONOXIDE Nickel sulfate hexahydrate (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Triphenylphosphine
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