(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE

(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Basic information
Reactions
Product Name:(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
Synonyms:(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE;(R,R)-ME-BPE;Bisdimethylphospholanoethane;(+)-1,2-Bis[(2R,5R)-2,5-dimethyphospholano]ethane, Kanata purity;(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane,98+%(R,R)-Me-BPE;(+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane,95%;1,2-Bis[(2R,5R)-2,5-diMethyl-1-phospholanyl]ethane, 97+%;(+)-1,2-Bis((2R,5R)-2,5-diMethylphospholano)ethane (R,R)-Me-BPE
CAS:129648-07-3
MF:C14H28P2
MW:258.32
EINECS:
Product Categories:organophosphine ligand
Mol File:129648-07-3.mol
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Structure
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Chemical Properties
alpha +263° ±3° (c 1, hexane)
Boiling point 64-67 °C 0.06 mm Hg
density 0.940 g/mL at 25 °C
refractive index n20/D 1.534
form liquid
color colorless to pale-yellow
Sensitive Air Sensitive
CAS DataBase Reference129648-07-3
Safety Information
Hazard Codes F
Risk Statements 11-17
Safety Statements 24/25
RIDADR UN 2845 4.2/PG 1
WGK Germany 3
HazardClass 4.2
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Usage And Synthesis
ReactionsThe DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Reactions of 129648-07-3
Chemical PropertiesClear colorless oily liquid
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Preparation Products And Raw materials
Ethanol Metformin hydrochloride Ethyl acetate (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE (+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)trifluoromethanesulfonate (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE 1,2-BIS((2S,5S)-2,5-DIISOPROPYLPHOSPHOLANO)ETHANE (+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE (+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)trifluoromethanesulfonate (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

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