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O-TOLYLMAGNESIUM BROMIDE

O-TOLYLMAGNESIUM BROMIDE Basic information
Product Name:O-TOLYLMAGNESIUM BROMIDE
Synonyms:O-TOLYLMAGNESIUM BROMIDE;bromo-o-tolylmagnesium;O-TOLYLMAGNESIUM BROMIDE, 2.0M SOLUTION IN DIETHYL ETHER;o-tolylmagnesium bromide solution;O-TOLYLMAGNESIUM BROMIDE: 19% IN THF, 1M/L;o-Tolylmagnesium Bromide (19% in Tetrahydrofuran, ca. 1mol/L);2-Methylphenylbromomagnesium;Bromo(2-methylphenyl) magnesium
CAS:932-31-0
MF:C7H7BrMg
MW:195.34
EINECS:213-250-2
Product Categories:Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Aryl;Grignard Reagents;Organometallic Reagents;Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals
Mol File:932-31-0.mol
O-TOLYLMAGNESIUM BROMIDE Structure
O-TOLYLMAGNESIUM BROMIDE Chemical Properties
density 1.013 g/mL at 25 °C
Fp −40 °F
form Solution
color Gray to brown
InChIKeyDVXDIGKNJYSMFM-UHFFFAOYSA-M
CAS DataBase Reference932-31-0
Safety Information
Hazard Codes F+,C,F
Risk Statements 12-14-20/21/22-34-40-67-22-19-11
Safety Statements 16-26-33-36/37/39-45
RIDADR UN 3399 4.3/PG 1
WGK Germany 3
HazardClass 3/8
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
O-TOLYLMAGNESIUM BROMIDE Usage And Synthesis
Chemical PropertiesYellow to brown liquid
Uses2-Tolylmagnesium Bromide is an intermediate used in the synthesis of 13-Fluorodibenzo[a,i]pyrene (F588440), which is a polycyclic aromatic hydrocarbon (PAH) thus potentially exhibiting carcinogenic properties through activation of P450 mono-oxygenase enzymes. Also, it has unique electrical and optical properties due to being a conjugated macromolecule.
O-TOLYLMAGNESIUM BROMIDE Preparation Products And Raw materials
Preparation ProductsBIS(O-TOLYL)PHOSPHINE-->2-Methylbenzhydryl chloride-->2-Methylbenzene-1-sulfonamide-->Benzeneacetic acid, 2-methyl-α-phenyl--->Benzene, 1-[(4-bromophenyl)sulfonyl]-2-methyl-
3-FLUOROPHENYLMAGNESIUM BROMIDE 3-FLUORO-2-METHYLPHENYLMAGNESIUM BROMIDE 4-METHOXY-2-METHYLPHENYLMAGNESIUM BROMIDE (2-(1-PYRROLIDINYLMETHYL)PHENYL)MAGNESIUM BROMIDE 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE 2-BIPHENYLMAGNESIUM BROMIDE 2,3-DIMETHYLPHENYLMAGNESIUM BROMIDE 5-FLUORO-2-METHYLPHENYLMAGNESIUM BROMIDE 2,4,5-TRIMETHYLPHENYLMAGNESIUM BROMIDE 4-FLUORO-2-METHYLPHENYLMAGNESIUM BROMIDE (2-(4-MORPHOLINYLMETHYL)PHENYL)MAGNESIU& 2-ETHYLPHENYLMAGNESIUM BROMIDE 2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE M-TOLYLMAGNESIUM BROMIDE: 19% IN TETRAHYDROFURAN, 1M),m-Tolylmagnesium Bromide (19% in Tetrahydrofuran, ca. 1mol/L),M-TOLYLMAGNESIUM BROMIDE 4-CHLORO-2-METHYLPHENYLMAGNESIUM BROMID& 2,3,5,6-TETRAMETHYLPHENYLMAGNESIUM BROMIDE 2,4,6-TRIMETHYLPHENYLMAGNESIUM BROMIDE 2,3,4,5,6-PENTAMETHYLPHENYLMAGNESIUM BROMIDE
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