2-AMINOANTHRAQUINONE

2-AMINOANTHRAQUINONE Basic information
Product Name:2-AMINOANTHRAQUINONE
Synonyms:2-Aminoanthraquinone technical grade;10-Anthracenedion;B-ANTHRAQUINONYLAMINE;AKOS NCG-0048;ANTHRAQUINONYLAMINE;2-AMINOANTHRAQUINONE;.beta.-Aminoanthraquinone;10-Anthracenedione,2-amino-9
CAS:117-79-3
MF:C14H9NO2
MW:223.23
EINECS:204-208-4
Product Categories:Building Blocks;C13 to C14;Aminoanthraquinones;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Intermediates of Dyes and Pigments;Anthraquinones;C13 to C14;Carbonyl Compounds;Ketones
Mol File:117-79-3.mol
2-AMINOANTHRAQUINONE Structure
2-AMINOANTHRAQUINONE Chemical Properties
Melting point 292-295 °C (dec.)(lit.)
Boiling point 364.52°C (rough estimate)
density 1.1814 (rough estimate)
refractive index 1.4700 (estimate)
Fp 283°C
solubility ethanol: soluble(lit.)
pka0.97±0.20(Predicted)
form solid
color Brown
Water Solubility 163ug/L(25 ºC)
BRN 745903
Stability:Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference117-79-3(CAS DataBase Reference)
IARC3 (Vol. 27, Sup 7) 1987
EPA Substance Registry System2-Aminoanthraquinone (117-79-3)
Safety Information
Hazard Codes Xn
Risk Statements 40
Safety Statements 36/37/39
WGK Germany 3
RTECS CB5120000
TSCA Yes
PackingGroup II
HS Code 2922290090
Hazardous Substances Data117-79-3(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
2-AMINOANTHRAQUINONE Usage And Synthesis
Chemical Properties2-Aminoanthraquinone forms red or orangebrown needle-shaped crystalline solid. It is used as an intermediate for dyes and pharmaceuticals.
Uses2- Amino-3-hydroxyanthraquinone is an intermediate for CI Vat Red 10.
Uses2-Aminoanthraquinone was used in fabrication of high performance electrode of supercapacitor based on chemically modified graphene hydrogel. It was used in preparation of ordered assemblies of organic and biological molecules on gold(111) surfaces.
DefinitionChEBI: 2-Aminoanthraquinone is an anthraquinone.
General Description2-aminoanthraquinone appears as red needle-like crystals or dark brown granular solid. (NTP, 1992)
Air & Water ReactionsInsoluble in water.
Reactivity Profile2-AMINOANTHRAQUINONE may react with strong oxidizing agents. Forms salts with mineral acids. Can be acylated or alkylated on the nitrogen atom and nitrated or sulgonated in the ring .
HazardQuestionable carcinogen.
Health HazardACUTE/CHRONIC HAZARDS: 2-AMINOANTHRAQUINONE may be absorbed through the skin and may cause irritation. It is a positive animal carcinogen. When heated to decomposition 2-AMINOANTHRAQUINONE emits toxic fumes of carbon monoxide, carbon dioxide and nitrogen oxides.
Fire HazardFlash point data for 2-AMINOANTHRAQUINONE are not available; however, 2-AMINOANTHRAQUINONE is probably combustible.
Safety ProfileConfirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Moderately toxic via intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic NO,. See also AMINES.
Potential Exposure2-Aminoanthraquinone is used as a dye intermediate; in the industrial synthesis of anthraquinone and pharmaceuticals. It is the precursor of five dyes and one pigment, including Color Index Vat Blues 4, 6, 12, and 24; Vat Yellow 1; and Pigment Blue 22. Because AAQ is used on a commercial scale solely by the dye industry, the potential for exposure to the compound is greatest for workers at dye manufacturing facilities. However, no additional data are available on the number of facilities using AAQ. The Consumer Product Safety Commission staff believes that trace amounts of unreacted AAQ may possibly be present in some dyes based on this chemical and in the final consumer product. Exposure even to trace amounts may be a cause for concern. This concern is based on experience with other dyes derived from aromatic amines.
Carcinogenicity2-Aminoanthraquinone is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
ShippingUN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
IncompatibilitiesKeep away from strong oxidizing and reducing agents. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides
1-AMINOANTHRAQUINONE DIAZO SALT 2-AMINOANTHRAQUINONE Acid Blue 129 REACTIVE BLUE 4 1-AMINO-2-METHYLANTHRAQUINONE ACID VIOLET 34 Solvent Green 3 Acid Green 25 ACID BLUE 80 1,4-BIS(1-ANTHRAQUINONYLAMINO)-ANTHRAQUINONE 1,4-Diamino anthraquinone 1-AMINO-4-BROMO-2-METHYLANTHRAQUINONE UNIBLUE A SODIUM SALT ACID BLUE 25 1,5-DIAMINO-4,8-DIHYDROXYANTHRAQUINONE Disperse Blue 14 1,2-DIAMINOANTHRAQUINONE ACID GREEN 27 (C.I. 61580)

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