BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE

BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE Basic information
Product Name:BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE
Synonyms:N-[chloro(dimethylamino)phosphoryl]-N-methylmethanamine;Bis(diMethylaMino)phosphoryl chloride, 90%, tech.;Bis(diMethylaMino)phosphoryl chloride, tech.;Bis(N,N-diMethylaMino)phosphinic chloride SynonyMs Bis(diMethylaMino)chlorophosphine oxide;N,N,N',N'-Tetramethylphosphorodiamidic chloride technical grade, 90%;Bis(dimethylamino)phosphorylchloride,95+%;bis-(N,N-dimethylamino)-phosphorylchloride;Phosphorodiamidic chloride, N,N,N',N'-tetramethyl-
CAS:1605-65-8
MF:C4H12ClN2OP
MW:170.58
EINECS:216-517-1
Product Categories:organophosphorus compound
Mol File:1605-65-8.mol
BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE Structure
BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE Chemical Properties
Boiling point 246-247 °C
density 1.152 g/mL at 25 °C(lit.)
refractive index n20/D 1.466(lit.)
Fp >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Chloroform (Sparingly), Ethyl Acetate (Slightly)
pka-0.04±0.70(Predicted)
form Liquid
color Colorless
Specific Gravity1.18
Sensitive Moisture Sensitive
BRN 471430
CAS DataBase Reference1605-65-8(CAS DataBase Reference)
EPA Substance Registry SystemPhosphorodiamidic chloride, tetramethyl- (1605-65-8)
Safety Information
Hazard Codes C
Risk Statements 34-37-20/21/22
Safety Statements 26-36/37/39-45
RIDADR UN 3265 8/PG 2
WGK Germany 3
HazardClass 8
PackingGroup III
HS Code 29299090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID
UsesN,N,N′,N′-Tetramethylphosphorodiamidic chloride was used in the synthesis of (-)-allohedycaryol and C2-symmetric binaphthyl phosphortriamide. It was also used in total synthesis of neohedycaryol.
BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE Preparation Products And Raw materials
Preparation ProductsDIMEFOX-->Phosphorodiamidic acid, tetramethyl-, ethyl ester-->Phosphorodiamidic acid, N,N,N',N'-tetramethyl--->CHLORODIMETHYLAMINE-->Hexamethylphosphoramide-->(Phosphoric diethyl)N,N,N',N'-tetramethyldiamidophosphoric anhydride-->Bis(N,N-dimethylamino)-pentachloro-phenyl phosphate
BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE Bis(2-oxo-3-oxazolidinyl)phosphinic chloride BIS(DIETHYLAMINO)PHOSPHOROCHLORIDATE BIS(DIMETHYLAMINO)CHLOROPHOSPHINE

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