ChemicalBook Product Catalog Chemical Reagents Silane reagent 1-PHENYL-2-(TRIMETHYLSILYL)ACETYLENE

1-PHENYL-2-(TRIMETHYLSILYL)ACETYLENE

1-PHENYL-2-(TRIMETHYLSILYL)ACETYLENE Basic information
Product Name:1-PHENYL-2-(TRIMETHYLSILYL)ACETYLENE
Synonyms:1-Phenyl-2-trimethylsilylacetylene,1-(Trimethylsilyl)-2-phenylacetylene, Phenylethynyl-trimethylsilane, Trimethyl(phenylethynyl)silane;1-PHENYL-2-TRIMETHYLSILYLACETYLENE 99%;2-Phenyl-1-(trimethylsilyl)acetylene;2-Phenyl-1-ethynyltrimethylsilane;Phenyl(trimethylsilyl)ethyne;TIMTEC-BB SBB008976;PHENYLETHYNYL-TRIMETHYLSILANE;1-Phenyl-2-TrimethylsilylacetylenePhenylethynyl trimethyl silane
CAS:2170-06-1
MF:C11H14Si
MW:174.31
EINECS:
Product Categories:Si-(C)4 Compounds;Acetylenes;Ethynylsilanes;Functionalized Acetylenes;Si (Classes of Silicon Compounds)
Mol File:2170-06-1.mol
1-PHENYL-2-(TRIMETHYLSILYL)ACETYLENE Structure
1-PHENYL-2-(TRIMETHYLSILYL)ACETYLENE Chemical Properties
Boiling point 87-88 °C9 mm Hg(lit.)
density 0.886 g/mL at 25 °C(lit.)
refractive index n20/D 1.528(lit.)
Fp 165 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Sparingly Soluble (6.1E-3 g/L) (25°C)
form Liquid
color Colorless
Specific Gravity0.886
Hydrolytic Sensitivity1: no significant reaction with aqueous systems
BRN 3088678
InChIKeyUZIXCCMXZQWTPB-UHFFFAOYSA-N
CAS DataBase Reference2170-06-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39
RIDADR NA 1993 / PGIII
WGK Germany 3
F 8
TSCA No
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
1-PHENYL-2-(TRIMETHYLSILYL)ACETYLENE Usage And Synthesis
Uses1-Phenyl-2-trimethylsilylacetylene was used in the preparation of donor-stabilized Pt-η2-alkyne complexes.
General Description1-Phenyl-2-trimethylsilylacetylene is an SiMe3-substituted alkyne. It undergoes coupling with propargylic and allylic alcohols. Polymerization of 1-phenyl-2-trimethylsilylacetylene by various transition metal catalysts has been reported.
1-PHENYL-2-(TRIMETHYLSILYL)ACETYLENE Preparation Products And Raw materials
Preparation Products3-TRIMETHYLSILYL-2-PROPYN-1-OL-->4-(2-PHENYLETH-1-YNYL)BENZALDEHYDE-->2,2-DICHLOROACETOPHENONE-->Phenylacetylene
TRIETHOXY-P-TOLYLSILANE 97 DIVINYLTETRAPHENYLDISILOXANE (p-Chlorophenyl)Trimethoxysilane NA (3-BROMOPHENYLETHYNYL)TRIMETHYLSILANE TRIMETHYLSILANE BIS(PHENYLETHYNYL)DIMETHYLSILANE ((4-(4-Propyl-2,6,7-trioxabicyclo(2.2.2)oct-1-yl)phenyl)ethynyl)trimet hylsilane ((4-(4-Butyl-2,6,7-trioxabicyclo(2.2.2)oct-1-yl)phenyl)ethynyl)trimeth ylsilane (3,5-BIS(TRIFLUOROMETHYL)PHENYLETHYNYL)& 1-(3',5'-DINITROPHENYL)-2-TRIMETHYLSILYLACETYLENE ((4-(4-Cyclohexyl-2,6,7-trioxabicyclo(2.2.2)oct-1-yl)phenyl)ethynyl)tr imethylsilane 1-(4'-NITROPHENYL)-2-TRIMETHYLSILYL ACETYLENE 2-TRIMETHYLSILYLETHYNYLTOLUENE 1-TRIMETHYLSILYLETHYNYL-3-FLUOROBENZENE ((4-(4-Pentyl-2,6,7-trioxabicyclo(2.2.2)oct-1-yl)phenyl)ethynyl)trimet hylsilane (4-(TRIFLUOROMETHYL)PHENYL)(TRIMETHYLSILYL)ACETYLENE PHENYLETHYNYL TRIMETHYLSILANE
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