CYCLOPROPYLTRIPHENYLPHOSPHONIUM BROMIDE

CYCLOPROPYLTRIPHENYLPHOSPHONIUM BROMIDE Basic information
Product Name:CYCLOPROPYLTRIPHENYLPHOSPHONIUM BROMIDE
Synonyms:Cyclopropyl(triphenyl)phosphonium bromide 95+%;Cyclopropyltriphenylphosphonium bromide 98%;Cyclopropyltriphenylphosphonium bromide 98% min;NSC 110599;CYCLOPROPYLTRIPHENYLPHOSPHONIUM BROMI;CYCLOPROPYLTRIPHENYLPHOSPHONIUM BROMIDE;CYCLOPROPANE TRIPHENYLPHOSPHONIUM BROMIDE;Phosphonium, cyclopropyltriphenyl-, bromide (1:1)
CAS:14114-05-7
MF:C21H20BrP
MW:383.26
EINECS:237-970-1
Product Categories:Cyclopropanes;Phosphonium Compounds;Simple 3-Membered Ring Compounds;Synthetic Organic Chemistry;Wittig & Horner-Emmons Reaction;Wittig Reaction;C-C Bond Formation;Olefination;Wittig Reagents
Mol File:14114-05-7.mol
CYCLOPROPYLTRIPHENYLPHOSPHONIUM BROMIDE Structure
CYCLOPROPYLTRIPHENYLPHOSPHONIUM BROMIDE Chemical Properties
Melting point 178-181 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
form solid
color White to Almost white
Water Solubility Soluble in water.
Sensitive Hygroscopic
BRN 6413483
InChIKeyXMPWFKHMCNRJCL-UHFFFAOYSA-M
CAS DataBase Reference14114-05-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
3-10
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
CYCLOPROPYLTRIPHENYLPHOSPHONIUM BROMIDE Usage And Synthesis
Chemical Propertieswhite to slightly yellowish crystalline powder
UsesCyclopropyltriphenylphosphonium bromide has cytotoxic activity against the growth of tissue culture cells originating from human epidermoid carcinoma of the nasopharynx (KB). It is commonly used as a Wittig reagent.
UsesUsed for electrolytic polarization of Zn

Studied for potential antitumor activity

Reactant for synthesis of:
  • Keto halides for sequential azidation and intramolecular Schmidt reactions
  • Cycloporpylidenemethylarylethynynes
  • Dipeptides containing azabicyclo[3.1.0]hexane

Reactant for hydroalkynylation
CYCLOPROPYLTRIPHENYLPHOSPHONIUM BROMIDE Preparation Products And Raw materials
(2-HYDROXYETHYL)TRIPHENYLPHOSPHONIUM BROMIDE Ethyltriphenylphosphonium bromide CYCLOPROPYLTRIPHENYLPHOSPHONIUM BROMIDE Methyltriphenylphosphonium bromide Propyltriphenylphosphonium bromide DIPHENYL-N-PROPYLPHOSPHINE ISOPROPYLDIPHENYLPHOSPHINE TETRAMETHYLPHOSPHONIUM BROMIDE Triphenylphosphine Triphenylphosphine hydrobromide

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