METANIL YELLOW

METANIL YELLOW Basic information
Product Name:METANIL YELLOW
Synonyms:3-((4-(phenylamino)phenyl)azo)-benzenesulfonicacimonosodiumsalt;3-[[4-(phenylamino)phenyl]azo]-benzenesulfonicacimonosodiumsalt;METANIL YELLOW ORANGE;METANIL YELLOW;KITON ORANGE MNO;KITON YELLOW MS;CI 13065;CI NO 13065
CAS:587-98-4
MF:C18H15N3O3S.Na
MW:377.39
EINECS:209-608-2
Product Categories:Azo;Organics;Analytical Chemistry;Indicator (pH);pH Indicators
Mol File:587-98-4.mol
METANIL YELLOW Structure
METANIL YELLOW Chemical Properties
Melting point >250°C
Boiling point 325℃[at 101 325 Pa]
density 0.488[at 20℃]
vapor pressure 0Pa at 25℃
storage temp. room temp
solubility 25g/l
form Powder
Colour Index 13065
color Orange
PH10 (10g/l, H2O, 20℃)
PH RangeRed (1.2) to yellow (2.3)
Water Solubility Soluble in water (25g/L).
λmax414nm, 435nm
Merck 14,5928
BRN 3831568
Major ApplicationDisplay device, nanoparticles, optical sensors, batteries, lithographic printing plates, inks, highlighters, children’s coloring books, floor coatings, disinfectants, dyes, personal care products, cosmetics, food storage, antiseptic, dental impressionmaterials
LogP0.137 at 25℃
CAS DataBase Reference587-98-4(CAS DataBase Reference)
EPA Substance Registry SystemC.I. Acid Yellow 36, monosodium salt (587-98-4)
Safety Information
Hazard Codes Xi
Risk Statements 43-36/37/38
Safety Statements 22-24/25-36/37-36-26
WGK Germany 2
RTECS DB7329500
TSCA Yes
HS Code 32041200
ToxicityLD50 orally in Rabbit: > 2000 mg/kg LD50 dermal Rat > 2000 mg/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
METANIL YELLOW Usage And Synthesis
DescriptionMetanil yellow is a yellow monoazo dye. This coloring agent is used in leather and wood stains, and was also employed as a food dye in India.
Chemical Propertiesorange powder
UsesAs indicator in 0.1% solution, of which 2 drops are required for 10 ml liquid. pH: 1.2 red to 2.3 yellow.
UsesMetanil Yellow is used as indicator. Metanil yellow is useful in spectrophotometric methods to determine the presence of trace amounts of nitrates and nitrites in solution. The method utilizes the fact that potassium bromate can catalyze the discoloring of Metanil yellow which can then be analyzed by spectrophotometry.
Usesdye used in leather; as indicator (pH) in laboratories
DefinitionChEBI: An organic sodium salt having 3-[(4-anilinophenyl)diazenyl]benzene-1-sulfonate as the counterion. Used in one variant of Masson's trichrome to stain collagen yellow in contrast to the red muscle, but is not in common used.
General DescriptionMetanil yellow is an azo dye, which is used as a counterstain in PAS (periodic acid-Schiff) or iron-hematoxylin stained sections to increase contrast. At pH 1.2, metanil yellow is red in color, whereas in pH 2.3, it is yellow in color.
Flammability and ExplosibilityNotclassified
Biochem/physiol ActionsMetanil yellow is an azo dye. It is used as a counterstain in PAS (periodic acid-Schiff)/iron-hematoxylin stained sections to increase contrast. Metanil yellow changes its color from red at pH 1.2 to yellow at pH 2.3.
Contact allergensMetanil yellow is a yellow monoazoic dye. This color ing agent is used in leather and wood stains, and is also employed as a food dye in India.
Safety ProfileModerately toxic by intraperitoneal route. Experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of SOx, NOx, and NazO. See also AROMATIC AMINES and SULFONATES.
Properties and Applications

Standard

Light Fastness

Soaping

Persperation Fastness

Oxygen bleaching

Fastness to seawater

Fading

Stain

Fading

Stain

Fading

Stain

ISO

3

2

2-3

AATCC

3

1

4

5

1

Purification MethodsIt can be salted out from water three times with sodium acetate, then repeatedly extracted with EtOH [McGrew & Schneider J Am Chem Soc 72 2547 1950]. [Beilstein 16 II 168.]
METANIL YELLOW Preparation Products And Raw materials
Raw materialsMetanilic acid-->Diphenylamine-->Metanilic acid-->Diphenylamine
Preparation Products4-Aminodiphenylamine
Fluorescein Sodium ACID DYES DISPERSE DYE 3-Aminophenol Sodium metabisulfite METANIL YELLOW m-[(p-Aminophenyl)azo]benzenesulphonic acid METANIL YELLOW EX 4-(PHENYLAZO)DIPHENYLAMINE ACID YELLOW 7 LUXOL FAST BLUE ARN ACID BLUE 89 ERIO METANIL YELLOW U Benzenesulfonic acid sodium salt CALCOCID METANIL YELLOW MXXX DUPONT METANIL YELLOW CALCOCID METANIL YELLOW AMACID METANIL YELLOW

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