PRECOCENE II

PRECOCENE II Basic information
Product Name:PRECOCENE II
Synonyms:PRECOCENE II;6,7-DIMETHOXY-2,2-DIMETHYL-3-CHROMENE;6,7-dimethoxy-2,2-dimethyl-2h-1-benzopyra;6,7-dimethoxy-2,2-dimethyl-2h-benzo(b)pyran;ageratochromene;precocene2;6,7-dimethoxy-2,2-dimethyl2H-1-benzopyran;6,7-Dimethoxy-2,2-dimethylchromene
CAS:644-06-4
MF:C13H16O3
MW:220.26
EINECS:211-408-5
Product Categories:Intermediates & Fine Chemicals;Pharmaceuticals
Mol File:644-06-4.mol
PRECOCENE II Structure
PRECOCENE II Chemical Properties
Melting point 47.50C
Boiling point 301.2°C (rough estimate)
density 1.1455 (rough estimate)
refractive index 1.4740 (estimate)
Fp 113 °C
storage temp. -20°C Freezer
solubility Chloroform (Slightly), Methanol (Slightly)
form Solid
color Pale Green to Yellow
LogP3.380 (est)
CAS DataBase Reference644-06-4
EPA Substance Registry System2H-1-Benzopyran, 6,7-dimethoxy-2,2-dimethyl- (644-06-4)
Safety Information
RTECS DJ2527000
MSDS Information
PRECOCENE II Usage And Synthesis
Chemical PropertiesCrystalline Solid
UsesAnti-juvenile hormones found in plants that induce reversible precocious metamorphosis and sterilization in insects by suppressing the function of the corpora allata gland.
DefinitionChEBI: Precocene II is a member of chromenes. It has a role as a member of precocenes.
Synthesis Reference(s)Journal of Heterocyclic Chemistry, 25, p. 871, 1988 DOI: 10.1002/jhet.5570250333
Synthetic Communications, 20, p. 1347, 1990 DOI: 10.1080/00397919008052847
Tetrahedron Letters, 32, p. 7251, 1991 DOI: 10.1016/0040-4039(91)80489-S
Safety ProfileQuestionable carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.
PRECOCENE II Preparation Products And Raw materials
3,4-dihydroxystyrene 7-ETHOXY-6-METHOXY-2,2-DIMETHYLCHROMENE 1-ISOPROPOXYBENZENE 4-Ethoxyphenol (Z)-anethole 2,5-Dimethoxytoluene 2-Methoxyhydroquinone 4-TERT-BUTOXYPHENOL 7-METHOXY-2,2-DIMETHYL-3-CHROMENE 2,4,5-TRIMETHOXY TOLUENE 3,4-DIMETHOXYSTYRENE 1,4-Dimethoxybenzene 2-METHOXYSTYRENE 4-Methoxyphenol 4-Hydroxy-3-methoxystyrene 1,2,4-Benzenetriol 4-ALLYLOXYANISOLE 4-ISOPROPOXYPHENOL

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