ChemicalBook Product Catalog Organic Chemistry Phosphines 2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl

2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl

2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl Basic information
Reaction
Product Name:2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl
Synonyms:2-DIMETHYLAMINO-2'-(DIPHENYLPHOSPHINO)BIPHENYL;2-(DIPHENYLPHOSPHINO)-2'-(N,N-DIMETHYLAMINO)BIPHENYL;2-Diphenylphosphino-2;PhDave-Phos 97%;PhDavePhos;2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl,98%;(N,N-DIMETHYLAMINO)BIPHENYL;[1,1''-BIPHENYL]-2-AMINE, 2''-(DIPHENYLPHOSPHINO)-N,N-DIMETHYL-
CAS:240417-00-9
MF:C26H24NP
MW:381.45
EINECS:607-309-5
Product Categories:Achiral Phosphine;Aryl Phosphine;Phosphines;Biphenyl & Diphenyl ether;Buchwald Ligands Series;Buchwald Ligands&Precatalysts
Mol File:240417-00-9.mol
2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl Structure
2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl Chemical Properties
Melting point 126-128 °C
Boiling point 514.6±43.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
pka4.96±0.18(Predicted)
form Powder, Crystals, Crystalline Powder and/or Chunks
color White to yellow
Water Solubility insoluble
InChIKeyJGFXUYLYPITYGR-UHFFFAOYSA-N
CAS DataBase Reference240417-00-9
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 37/39-26-36/37/39
WGK Germany 3
TSCA No
HazardClass IRRITANT
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl Usage And Synthesis
Reaction
  1. Useful ligand for sterically hindered substrates in the Pd-catalyzed amination reactions of aryl bromides.
  2. Ligand used for the Cu-catalyzed phosphorylation of alcohols.
  3. Ligand for Pd-catalyzed C-H benzylation.
  4. Ligand for palladium-catalyzed [4 + 2] benzannulation reaction.
Reactions of 240417-00-9
Chemical Propertieswhite to yellow powder, crystals, crystalline
Usessuzuki reaction
2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl Preparation Products And Raw materials
Raw materials[1,1'-Biphenyl]-2-amine, 2'-(diphenylphosphinyl)-N,N-dimethyl--->1-Bromo-2-iodobenzene
2-Dicyclohexylphosphino-2',6'-bis(diMethylaMino)-1,1'-biphenyl, Min. 98% Cphos 2-DIPHENYLPHOSPHINO-6-METHYLPYRIDINE 2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL 2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRIISO& 2'-(Dicyclohexylphosphino)-N,N-dimethyl[1,1'-biphenyl]-4-amine 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl 2-(Dicyclohexylphosphino)-2'-methylbiphenyl 2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl Diphenylphosphine Diphenyldimethoxysilane Biphenyl 4-Dimethylaminobenzoic acid 4-Dimethylaminobenzaldehyde 3-Dimethylaminopropylamine 2-Dimethylaminoethanol Chlorodiphenylphosphine 4-Dimethylaminopyridine
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