7,8-BENZOQUINOLINE

7,8-BENZOQUINOLINE Basic information
?Hazardous Properties
Product Name:7,8-BENZOQUINOLINE
Synonyms:BENZO[H]QUINOLINE;A-NAPHTHOQUINOLINE;ALPHA-NAPHTHOQUINOLINE;7,8-BENZOQUINOLINE;4-AZAPHENANTHRENE;1-NAPHTHOQUINOLINE;7,8-Benzoquinoline~alpha-Naphthoquinoline;7,S-Benzochinolin
CAS:230-27-3
MF:C13H9N
MW:179.22
EINECS:205-937-0
Product Categories:Thiophenes ,Thiazolines/Thiazolidines;API intermediates
Mol File:230-27-3.mol
7,8-BENZOQUINOLINE Structure
7,8-BENZOQUINOLINE Chemical Properties
Melting point 48-50 °C(lit.)
Boiling point 338 °C719 mm Hg(lit.)
density 1.2340
refractive index 1.7270 (estimate)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
solubility almost transparency in Methanol
pkapK1: 4.15(+1) (20°C)
form Crystalline Powder
color Off-white to brown
BRN 120249
CAS DataBase Reference230-27-3(CAS DataBase Reference)
NIST Chemistry ReferenceBenzo[h]quinoline(230-27-3)
EPA Substance Registry SystemBenzo[h]quinoline (230-27-3)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 22-24/25-36-26
WGK Germany 3
RTECS DK1432000
HS Code 29339900
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
7,8-BENZOQUINOLINE Usage And Synthesis
?Hazardous Properties7,8-Benzoquinoline is combustible; burns to produce toxic fumes of nitrogen oxides.
Physical properties7,8-Benzoquinoline is a dark yellow crystalline solid.
UsesBenzo[h]quinoline was used to study the mutagenic activities of benzo[f]quinoline, benzo[h]quinolone and a number of their derivatives in strain TA 100 of Salmonella typhimurium. It was used in determination of nitrogen-containing polynuclear aromatic hydrocarbons in the gaseous products of the thermal degradation of polymers by HPLC- fluorescence detection. It was used as starting reagent for the synthesis of osmium and ruthenium complexes containing an N-heterocyclic carbene ligand.
Safety ProfileMutation data reported. Whenheated to decomposition it emits toxic fumes of NOx.
Purification MethodsPurify it as for 3,4-benzoquinoline above. The picrate has m 196o(from Me2CO). [Beilstein 20 H 463, 20 III/IV 4003, 20/8 V 215.]
7,8-BENZOQUINOLINE DIBENZ[C,H]ACRIDINE SANGUINARINE SULFATE CHELERYTHRINE CHLORIDE DIBENZ(A,H)ACRIDINE SANGUINARINE CHLORIDE Nitidine chloride BENZO(C)ACRIDINE 4-HYDROXYBENZO[H]QUINOLINE-3-CARBOXYLIC ACID ETHYL ESTER 7,10-DIMETHYLBENZ[C]ACRIDINE 2,4-DIMETHYLBENZO[H]QUINOLINE 10-AZABENZO(A)PYRENE Macleaya cordata extract 10-Hydroxybenzo[h]quinoline SANGUINARINE HCL DIHYDRATE 2-METHYL-BENZO[H]QUINOLIN-4-OL 7,9-DIMETHYLBENZ[C]ACRIDINE SANGUINARINE NITRATE

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