Methyl 2-bromobenzoate

Methyl 2-bromobenzoate Basic information

Product Name:	Methyl 2-bromobenzoate
Synonyms:	RARECHEM AL BF 0014;METHYL 2-BROMOBENZOATE;METHYL O-BROMOBENZOATE;2-BROMOBENZOIC ACID METHYL ESTER;2-bromo-benzoicacimethylester;Benzoicacid,2-bromo-,methylester;O-bromobenzoic acid, methyl ester;Methyl2-bromobenzoate,99%
CAS:	610-94-6
MF:	C8H7BrO2
MW:	215.04
EINECS:	210-241-5
Product Categories:	Aromatic Esters;Acids & Esters;Bromine Compounds;C8 to C9;Carbonyl Compounds;Esters
Mol File:	610-94-6.mol

Methyl 2-bromobenzoate Chemical Properties

Melting point	252°C
Boiling point	252 °C (lit.)
density	1.532 g/mL at 25 °C (lit.)
refractive index	n20/D 1.559(lit.)
Fp	>230 °F
storage temp.	Sealed in dry,Room Temperature
form	Liquid
color	Clear light yellow
Specific Gravity	1.532
Water Solubility	insoluble
BRN	1862501
InChIKey	SWGQITQOBPXVRC-UHFFFAOYSA-N
CAS DataBase Reference	610-94-6(CAS DataBase Reference)
NIST Chemistry Reference	Methyl-2-bromobenzoate(610-94-6)
EPA Substance Registry System	Benzoic acid, 2-bromo-, methyl ester (610-94-6)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	24/25
WGK Germany	3
TSCA	Yes
HS Code	29163990

MSDS Information

Provider	Language
Methyl 2-bromobenzoate	English
SigmaAldrich	English
ACROS	English
ALFA	English

Methyl 2-bromobenzoate Usage And Synthesis

Chemical Properties	CLEAR LIGHT YELLOW LIQUID
Uses	Methyl 2-bromobenzoate under Heck reaction with acrylonitrile results in lactonization to give the benzofuran-2-one 3-(cyanomethyl)-2-coumaranone. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals
Purification Methods	A solution of the ester in ether is washed with 10% aqueous Na 2CO3, water, then dried and distilled. [Beilstein 9

Methyl 2-bromobenzoate Preparation Products And Raw materials

Raw materials	carbon monoxide-->2-Bromobenzyl alcohol-->2'-Bromoacetophenone-->Methyl benzoate-->tert-Butyl hydroperoxide-->1-Bromo-2-iodobenzene-->1-Bromobenzyl methyl ether-->2-Bromotoluene-->Phthalic acid-->Methanol
Preparation Products	METHYL BIPHENYL-2-CARBOXYLATE-->3,3-diMethyl-6-nitrobenzo[c][1,2]oxaborol-1(3H)-ol

Methyl 2-bromobenzoate TERT-BUTYL-2-BROMOBENZOATE Methyl Ethyl 2-bromobenzoate 4-Bromobenzoic acid 2-Bromobenzoic acid ISOPROPYL 2-BROMOBENZOATE Bensulfuron methyl Parathion-methyl METHYL 6-BROMO-3,4-DIMETHOXYBENZOATE Tetrabromophthalic anhydride 4-Bromomethylbenzoic acid 3,3'-(4,5,6,7-tetrabromo-3-oxo-1(3H)-isobenzofuranylidene)bis[6-hydroxybenzenesulphonic] acid Ethyl 2-bromo-3-nitrobenzoate Methyl benzoate Methyl acrylate Methyl 2-bromo-5-nitrobenzoate Anthranilic acid

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