Ammonium iodide

Ammonium iodide Basic information
Description References
Product Name:Ammonium iodide
Synonyms:Azanium iodide;Ammonium iodide, for analysis;Ammonium iodide,99+%,for analysis;Ammonium iodide, ACS min;Ammonium iodide/ 99.9%;AMMoniuM iodide, 99%, extra pure;AMMoniuM iodide, 99.995% (Metals basis);Ammonium iodide 99.999% trace metals basis
CAS:12027-06-4
MF:H4IN
MW:144.94
EINECS:234-717-7
Product Categories:Routine Reagents;A-B, Puriss p.a. ACS;Analytical Reagents for General Use;Puriss p.a. ACS;Ammonium Salts;AmmoniumMetal and Ceramic Science;ACS GradeSynthetic Reagents;Ammonium;Essential Chemicals;Inorganic Salts;Salts;Synthetic Reagents;AmmoniumAnalytical Reagents;Puriss;Inorganics;metal halide;Pharmaceutical Intermediates
Mol File:12027-06-4.mol
Ammonium iodide Structure
Ammonium iodide Chemical Properties
Melting point 551 °C (lit.)
Boiling point 405°C (estimate)
density 2.51
vapor pressure 1 mm Hg ( 210.9 °C)
refractive index 1.7031
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility ethanol: slightly soluble(lit.)
form Granular
pka0.31±0.70(Predicted)
Specific Gravity2.514
color White to pale yellow
OdorOdorless
PH4.5-6.5 (20℃, 5%)
PH Range4.5 - 6.5
Water Solubility Soluble in water, ethanol, methanol, acetone, ammonia and glycerol. Slightly soluble in ether.
Sensitive Light Sensitive & Hygroscopic
Merck 14,529
Exposure limitsACGIH: TWA 0.01 ppm
CAS DataBase Reference12027-06-4(CAS DataBase Reference)
NIST Chemistry ReferenceAmmonium iodide(12027-06-4)
EPA Substance Registry SystemAmmonium iodide ((NH4)I) (12027-06-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
3-8-10-23
TSCA Yes
HS Code 28276000
Hazardous Substances Data12027-06-4(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Ammonium iodide English
SigmaAldrich English
ACROS English
ALFA English
Ammonium iodide Usage And Synthesis
DescriptionAmmonium iodide (chemical formula:NH4I) is an inorganic compound consisting of ammonium and iodide. It can be prepared by the reaction between hydroiodic acid (or hydrogen iodide gas) with ammonia or ammonia hydroxide. It can be used in photographic chemicals and some medications. It can also be supplemented to many animal feed formulations as a dietary source of Iodine. It can be added to a release agent and being capable of increasing the throughput and success rate due to smoother bead release process, reducing damage to platinum ware due to forced bead release as well as reducing crucible cleaning requirement.
Referenceshttp://www.newalliance.co.in/prodhtml/Fine%20Chemicals/Bromides/B009%20Ammonium%20Iodide.html
https://en.wikipedia.org/wiki/Ammonium_iodide
http://www.xrfscientific.com/products/release-agent/

Chemical Propertieswhite to light yellow crystalline powder
UsesIt is used in photographic chemicals and some medications. It is a catalyst for dethioacetalization reaction.
UsesIn photographic chemicals.
UsesWhite crystals made by the action of ammonium hydroxide on hydroiodic acid followed by crystallization. Soluble in water and alcohol, ammonium iodide was used as a halide in collodion formulas, particularly in situations where it was needed for use immediately. Ammonium iodide decomposes quickly when mixed with plain collodion, releasing iodine.
DefinitionChEBI: The iodide salt of ammonia.
General DescriptionOdorless white solid. Sinks and mixes with water.
Air & Water ReactionsWater soluble.
Reactivity ProfileAmmonium iodide is light sensitive, becomes yellow or brown on exposure to air and light because of liberation of Iodine [Merck 11th ed. 1989]. Bromine trifluoride reacts explosively with the following ammonium bromide, ammonium chloride, Ammonium iodide [Mellor 2 Supp. 1:165 1956].
Health HazardInhalation causes irritation of nose and throat. Contact with eyes causes irritation.
Flammability and ExplosibilityNotclassified
Purification MethodsThe iodide crystallises from EtOH on addition of ethyl iodide, and is very hygroscopic. Store it in the dark. Its solubility is 177g in 100g of H2O at 25o. [Schmeisser in Handbook of Preparative Inorganic Chem (Ed. Brauer) Academic Press Vol I p 289-290 1963.]
Ammonium iodide Preparation Products And Raw materials
Raw materialsEthanol-->Nitric acid-->Ammonium hydroxide-->Ammonia-->Iodine-->Hydriodic acid-->Ammonium sulfide
Preparation Products4-CHLOROBENZAMIDINE HYDROIODIDE-->guanidine
Tetrabutylammonium iodide Ammonium iodide Ammonium hydroxide AMMONIUM Potassium iodide BISMUTH(III) IODIDE Liothyronine sodium 2'-IODOHIPPURIC ACID Ammonium nitrate 1,5-I-AEDANS 3-IODO-L-TYROSINE 3-Hydroxy-2-iodo-6-methylpyridine Tetramethylammonium iodide Ammonium chloride Propidium iodide 5-Iodouracil Molybdic acid Ammonium sulfate

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