PHENETHYLZINC BROMIDE

PHENETHYLZINC BROMIDE Basic information
Product Name:PHENETHYLZINC BROMIDE
Synonyms:PHENETHYLZINC BROMIDE;phenethylzinc bromide solution;Phenethylzinc bromide solution 0.5 in THF;PHENETHYLZINC BROMIDE, 0.5M SOLUTION IN;2-Phenylethylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles;Phenethylzinc bromide solution 0.5 M in THF;2-Phenylethylzinc bromide;Phenethylzinc bromide, 0.50 M in THF
CAS:308796-14-7
MF:C8H9BrZn
MW:250.45
EINECS:
Product Categories:Chemical Synthesis;Organometallic Reagents;Alkyl;Organozinc Halides;Organozinc Halides;Rieke and Organozinc Reagents;Reike and Organozinc Reagents
Mol File:308796-14-7.mol
PHENETHYLZINC BROMIDE Structure
PHENETHYLZINC BROMIDE Chemical Properties
Boiling point 65 °C
density 0.965 g/mL at 25 °C
Fp 1 °F
storage temp. 2-8°C
Water Solubility Reacts with water.
Sensitive Air Sensitive
Exposure limitsACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
CAS DataBase Reference308796-14-7
Safety Information
Hazard Codes F,Xn
Risk Statements 14-19-22-36/38-40-36/37-11
Safety Statements 16-26-33-36-36/37
RIDADR UN 2056 3/PG 2
WGK Germany 1
HazardClass 4.3
MSDS Information
ProviderLanguage
SigmaAldrich English
PHENETHYLZINC BROMIDE Usage And Synthesis
UsesPhenethylzinc bromide can be used as a reagent:
  • In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
  • To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
  • To synthesize benzyl substituted thienopyrimidine derivatives.

PHENETHYLZINC BROMIDE Preparation Products And Raw materials
2,4-DIFLUOROBENZYLZINC BROMIDE 4-METHYL-2-PYRIDYLZINC BROMIDE 2-PROPYLZINC BROMIDE SOLUTION 0.5M IN T& 2-TERT-BUTOXY-2-OXOETHYLZINC CHLORIDE 3-METHYL-2-PYRIDYLZINC BROMIDE 2-THIENYLZINC BROMIDE 3-CHLOROPHENETHYLZINC BROMIDE PHENETHYLZINC BROMIDE 3-METHOXYPHENETHYLZINC BROMIDE 4-METHYLPHENETHYLZINC BROMIDE 3-FLUOROPHENETHYLZINC BROMIDE 2-METHOXYPHENETHYLZINC BROMIDE 3-CHLORO-5-FLUOROPHENETHYLZINC BROMIDE 4-METHOXYPHENETHYLZINC BROMIDE 3-METHYLPHENETHYLZINC BROMIDE 4-FLUOROPHENETHYLZINC BROMIDE 4-CHLOROPHENETHYLZINC BROMIDE 2-METHYLPHENETHYLZINC BROMIDE

Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.