Silver mesylate

Silver mesylate Basic information
Product Name:Silver mesylate
Synonyms:SMS;SILVER MESYLATE;SILVER METHANESULFONATE;methanesulfonicacid,silver(1+)salt;METHANESULFONIC ACID, SILVER SALT;METHYLSULFONIC ACID SILVER SALT;methanesulfonicacid,silver(1++)salt;silver methanesulphonate
CAS:2386-52-9
MF:CH3AgO3S
MW:202.97
EINECS:219-199-2
Product Categories:Ag;Organic-metal salt
Mol File:2386-52-9.mol
Silver mesylate Structure
Silver mesylate Chemical Properties
Melting point 252-256 °C (lit.)
density 1.405 at 20℃
storage temp. Keep in dark place,Inert atmosphere,Room temperature
form Powder
color White to beige or light gray
PH1 at 20℃ and 10g/L
Water Solubility Soluble in water, alcohol, ether and benzene. Slightly soluble in toluene, o-chlorotoluene and ethyl disulfide. Insoluble in hexane and methylcyclopentane.
Sensitive Light Sensitive
InChIKeyMLKQJVFHEUORBO-UHFFFAOYSA-M
Surface tension77.8mN/m at 1g/L and 20℃
Dissociation constant1.9 at 20℃
CAS DataBase Reference2386-52-9(CAS DataBase Reference)
EPA Substance Registry SystemMethanesulfonic acid, silver(1+) salt (2386-52-9)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 26-36-36/37/39-22
RIDADR 1759
WGK Germany 3
RTECS PB2685000
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 28432900
MSDS Information
ProviderLanguage
Silver mesylate English
SigmaAldrich English
ACROS English
ALFA English
Silver mesylate Usage And Synthesis
Chemical Propertieswhite to beige or light grey crystalline powder
UsesGold Catalysts—21st Century'Gold Rush' Catalyst for: .Heterocyclization reactions . CO2-mediated rearrangement of propargyl alcohols for the synthesis of a,?-unsaturated ketones and esters
UsesSilver methanesulfonate is used as a catalyst for heterocyclization reactions. Further, it is used in the synthesis of unsaturated ketones and esters.
Safety ProfilePoison by intravenous route. When heated to decomposition it emits toxic fumes of SO,. See also SULFONATES and SILVER COMPOUNDS
Silver mesylate Preparation Products And Raw materials
Raw materialsSilver oxide-->Methanesulfonic acid
Preparation Productstributylstannyl methanesulfonate-->Acetic acid, 2-[(methylsulfonyl)oxy]-
Methanesulfonic anhydride Sodium methyl sulfate Sodium anthraquinone-2-sulfonate Ethyl 2-(Chlorosulfonyl)acetate Taurine Nitromethane SILVER TRIFLUOROMETHANESULFONATE Ascoric Acid Methanesulfonic acid Stearic acid Folic acid Chloroform Chlorosulfonic acid Mercury Imatinib Silver Methyl bromide Citric acid

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