Silicon monoxide

Silicon monoxide Basic information
Product Name:Silicon monoxide
Synonyms:Monox;oxo-silylen;Silylene, oxo-;SiO;silicon monooxide coating quality balzers;silicon monoxide coating quality balzers;SiliconIIoxidegranularmeshbrownpowder;SiliconIIoxidemeshbrownpowder
CAS:10097-28-6
MF:OSi
MW:44.09
EINECS:233-232-8
Product Categories:Metal and Ceramic Science;Oxides;Inorganic Chemicals;metal oxide
Mol File:10097-28-6.mol
Silicon monoxide Structure
Silicon monoxide Chemical Properties
Melting point 1870 °C
Boiling point 1880°C
density 2.13 g/mL at 25 °C (lit.)
refractive index 1.9800
Fp 1880°C
form powder
color Black
Specific Gravity2.13
Water Solubility Insoluble in water.
Hydrolytic Sensitivity1: no significant reaction with aqueous systems
Merck 14,8496
Stability:Stable.
CAS DataBase Reference10097-28-6(CAS DataBase Reference)
NIST Chemistry ReferenceSilicon monoxide(10097-28-6)
EPA Substance Registry SystemSilylene, oxo- (10097-28-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
TSCA Yes
MSDS Information
ProviderLanguage
Silicon monoxide English
SigmaAldrich English
ALFA English
Silicon monoxide Usage And Synthesis
Chemical PropertiesSilicon monoxide (SiO) is another oxide of silicon, used rarely in silicon processing but quite often in thin film, hybrid Ie manufacture. It is useful there because no silicon is available for in situ growth of the dioxide, and it is deposited easily by physical vapor deposition, a process quite similar to the vacuum deposition of aluminum described. Usually the condensed oxide is nonstoichiometric, being a mixture of SiO, Si02, and Si; often, it is designated SiOx .The value of x, which ranges between 1 and 2, is influenced by the deposition conditions.
The SiO source material is prepared by heating Si02 with Si, carbon, and hydrogen, or a hydrocarbon, to reduce the dioxide to the monoxide. Reduction takes place at roughly 1000°C, and SiO is formed in the vapor phase. This temperature is much too low to produce a significant vapor pressure of Si02, so the two oxides may be separated. The monoxide vapor is condensed out and subsequently powdered. This material, which is suitable for evaporation, is available commercially and need not be prepared by the IC manufacturer.
Chemical Propertiesbrown or black chunks or powder
UsesTo form thin surface films for protection of alu- minum coatings, optical parts, mirrors, dielectrics, or insulators.
UsesSilicon monoxide (SiO) is a commonly used material for a wide variety of applications with the emphasis on IR multilayer coatings and adhesion promotion. SiO sublimes and should preferably be evaporated from resistance heated boats.
AREAS OF APPLICATION
Multilayer coatings especially for the IR, but also the VIS range
Adhesion promoter (VIS, NIR)
Electronics: dielectric, insulating and protective layers
Design: iridescent coatings, colored metallically reflecting coatings e.g. on sun glasses
Web coating: barrier layers on polymer films





UsesSilicon(II) oxide sputtering target coatings are used for optical applications in reflectors, flood lamps, mirrors, jewelry, and other products. The coatings can reduce reflection in the near infrared range or act as interference layers. It is used in thin-film capacitors, hybrid circuits, semiconductor components and other electronic applications.
DefinitionChEBI: Silicon monoxide is a silicon oxide.
Silicon monoxide Preparation Products And Raw materials
Raw materialsArgon-->Silicon dioxide-->Coal tar pitch
Preparation ProductsSODIUM ALUMINUM OXIDE-->SILICONE RESIN
Silicon monoxide Silica glass CARBON MONOXIDE SILICON OXIDE, CATALYST SUPPORT, HIGH SURFACE AREA DIMETHYLSILOXANE, PROPYLENE OXIDE/ETHYLENE OXIDE BLOCK COPOLYMER NICKEL-CHROMIUM-SILICON MONOXIDE CHROMIUM SILICON MONOXIDE, 99.85+% (METALS BASIS),CHROMIUM SILICON MONOXIDE silicon PHENYLTRIACETOXYSILANE Chromium silicon monoxide, 99.8+% (metals basis),CHROMIUM SILICON MONOXIDE SILICON OXIDE, CATALYST SUPPORT, LOW SURFACE AREA tris(Trimethylsilyloxy)silanol MULLITE Silicon Rubber Quartz DIMETHYLSILOXANE, PROPYLENE OXIDE/ETHYLENE OXIDE BLOCK COPOLYMER Silica, fumed CHROMIUM SILICON MONOXIDE,CHROMIUM SILICON MONOXIDE, 99.9% (METALS BASIS)

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