|
| | 1-AZIDO-2,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOSE Basic information |
| Product Name: | 1-AZIDO-2,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOSE | | Synonyms: | 1-Azido-1-deoxy-beta-D-glucopyranosidetetraacetate98%;acetic acid (3,4,5-triacetyloxy-6-azido-2-oxanyl)methyl ester;[3,4,5-TRIS(ACETYLOXY)-6-AZIDOOXAN-2-YL]METHYL ACETATE;1-AZIDO-1-DEOXY-BETA-D-GLUCOPYRANOSIDE TETRAACETATE;1-AZIDO-2,3,4,6-O-ACETYL-BETA-D-GLUCOSE;1-AZIDO-2,3,4,6-TETRA-O-ACETYL-B-D-GLUCOSE;1-AZIDO-2,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOSE;2,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOPYRANOSYL AZIDE | | CAS: | 13992-25-1 | | MF: | C14H19N3O9 | | MW: | 373.32 | | EINECS: | | | Product Categories: | MonosaccharidesChemical Ligation;Carbohydrate Synthesis;Click Chemistry;Organic Azides;Specialty Synthesis;Carbohydrates;Sugars, Carbohydrates & Glucosides;Glycon Biochem | | Mol File: | 13992-25-1.mol |  |
| | 1-AZIDO-2,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOSE Chemical Properties |
| Melting point | 127-131 °C(lit.) | | Boiling point | 502.57°C (rough estimate) | | density | 1.3271 (rough estimate) | | refractive index | 1.5700 (estimate) | | form | crystals | | color | White | | optical activity | [α]/D -29°, c = 1% in H2O &_& [α]/D -30°, c = 1% in chloroform | | CAS DataBase Reference | 13992-25-1(CAS DataBase Reference) |
| Hazard Codes | Xi | | Risk Statements | 2-11 | | Safety Statements | 22-24/25 | | RIDADR | 1325 | | WGK Germany | 3 | | Hazard Note | Irritant | | HS Code | 29329990 |
| | 1-AZIDO-2,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOSE Usage And Synthesis |
| Chemical Properties | WHITE TO BEIGE CRYSTALLINE POWDER | | Uses | β-D-Glucopyranosyl Azide 2,3,4,6-Tetraacetate, is an intermediate used for the synthesis of Protein Tyrosine Phosphatase 1B inhibito1. It is used for the preparation of variously coupled conjugates of D-glucose via click chemistry for inhibition of glycogen phosphorylase. |
| | 1-AZIDO-2,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOSE Preparation Products And Raw materials |
| Raw materials | α-D-Glucopyranosyl bromide-->2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL CHLORIDE-->2,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOPYRANOSE-->2,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOPYRANOSYL BROMIDE-->2,3,4,6-Tetra-O-acetyl-beta-D-glucopyranosyl 2,2,2-Trichloroacetimidate-->2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide-->Glucose pentaacetate-->beta-D-Galactose pentaacetate-->β-D-Glucose pentaacetate-->D-glucose-->Acetone-->Acetic anhydride | | Preparation Products | beta-D-Glucopyranosylamine-->1-AZIDO-1-DEOXY-BETA-D-GLUCOPYRANOSIDE |
|
